ArticleNature communications2020
Solvent tuning of photochemistry upon excited-state symmetry breaking.
Article in Nature communications, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed.
- Phase-Resolved Dual Control of Phenol Photodissociation at the Air-Water Interface From Structure-Resolved Statistics.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Symmetry-breaking charge separation in perylene diimide trimers: effects of aggregation and solvent polarity.Chemical science · 2026Article
- Tracking polar solvation dynamics of a photoexcited organic chromophore with ultrafast X-ray scattering.Nature communications · 2026Article
- Vibronic coupling-driven symmetry breaking and solvation in the photoexcited dynamics of quadrupolar dyes.Nature chemistry · 2025Article
- Ion Translocation Driven by Electric Field Generated in Excited-State Reactions.Accounts of chemical research · 2025Article
- Barrierless Electron Transfer in a Photosynthetic Reaction Center Model.Angewandte Chemie (International ed. in English) · 2025Article
- Solvation controlled excited-state dynamics in a donor-acceptor phenazine-imidazole derivative.RSC advances · 2024Article
- Ultrafast symmetry-breaking charge separation in Perylenemonoimide-embedded multichromophores: impact of regioisomerism.Chemical science · 2024Article
- Symmetry breaking charge transfer leading to charge separation in a far-red absorbing bisstyryl-BODIPY dimer.Chemical science · 2024Article
- Unraveling Excited State Dynamics of a Single-Stranded DNA-Assembled Conjugated Polyelectrolyte.The journal of physical chemistry letters · 2023Article
- High-Efficiency Photoinduced Charge Separation in Fe(III)carbene Thin Films.Journal of the American Chemical Society · 2023Article
- Excited-state symmetry breaking in quadrupolar pull-push-pull molecules: dicyanovinylPhysical chemistry chemical physics : PCCP · 2023Article
- Ambipolar Charge Transport in Organic Semiconductors: How Intramolecular Reorganization Energy Is Controlled by Diradical Character.Molecules (Basel, Switzerland) · 2023Article
- Atomic-scale observation of solvent reorganization influencing photoinduced structural dynamics in a copper complex photosensitizer.Chemical science · 2023Article
- From symmetry breaking to symmetry swapping: is Kasha's rule violated in multibranched phenyleneethynylenes?Chemical science · 2023Article
- Reducing the internal reorganization energyChemical science · 2022Article
- Rethinking Uncaging: A New Antiaromatic Photocage Driven by a Gain of Resonance Energy.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- The Carbene Cannibal: Photoinduced Symmetry-Breaking Charge Separation in an Fe(III)Journal of the American Chemical Society · 2021Article
- Excited-state symmetry breaking in 9,10-dicyanoanthracene-based quadrupolar molecules: the effect of donor-acceptor branch length.Physical chemistry chemical physics : PCCP · 2021Article
- Porous shape-persistent rylene imine cages with tunable optoelectronic properties and delayed fluorescence.Chemical science · 2021Article
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The nature of the electronic excited state of many symmetric multibranched donor-acceptor molecules varies from delocalized/multipolar to localized/dipolar depending on the environment. Solvent-driven localization breaks the symmetry and traps the exciton in one branch. Using a combination of ultrafast spectroscopies, we investigate how such excited-state symmetry breaking affects the photochemical reactivity of quadrupolar and octupolar A-(π-D)
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