ArticleChemistry (Weinheim an der Bergstrasse, Germany)2020
Discoveries and Challenges en Route to Swinhoeisterol A.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Biogenetic space-guided synthesis of rearranged terpenoids.Chemical communications (Cambridge, England) · 2023Review
- Review
- Discoveries and Challenges en Route to Swinhoeisterol A.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
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Authors and funding
4 authors.
Funding
Abstract
In this work, a full account of the authors' synthetic studies is reported that culminated in the first synthesis of 13(14→8),14(8→7)diabeo-steroid swinhoeisterol A as well as the related dankasterones A and B, 13(14→8)abeo-steroids, and periconiastone A, a 13(14→8)abeo-4,14-cyclo-steroid. Experiments are described in detail that provided further insight into the mechanism of the switchable radical framework reconstruction approach. By discussing failed strategies and tactics towards swinhoeisterol A, the successful route that also allowed an access to structurally closely related analogues, such as Δ
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Registered trials
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