ArticleNature chemistry2020
Enhanced reactivity of twisted amides inside a molecular cage.
Article in Nature chemistry, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 66 papers.
What it found
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Who cites it
66 citing papers in PubMed.
- Confined Catalysis of Enzymes: Enhancement Strategies, Materials, and Biosensor Applications.Journal of functional biomaterials · 2026Review
- Two-dimensional p-π conjugated amide-linked polymeric photocatalysts with enhanced carrier separation.Nature communications · 2026Article
- Light-Induced Rotation of a Molecular Motor in the Confined Space of a Metal-Organic Nanocage.Journal of the American Chemical Society · 2026Article
- Piezofluorochromism in Aramid Dyads: Pressure-Triggered Luminescence Enhancement with Predictable Emission Shifts.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Synthesis of Primary Amines via Reductive Amination of Aldehydes and Ketones Over a Ni-Doped MFM-300(Cr) Catalyst.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Transformation of a PdChemical science · 2025Article
- Accessing Single-Molecule Properties of Heptacene Using a Metal-Organic Framework.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Fluoride Enhances Alcohol Binding Within a Trigonal-Prismatic Metal-Organic Capsule.Angewandte Chemie (International ed. in English) · 2025Article
- Supramolecular coordination cages as crystalline sponges through a symmetry mismatch strategy.Nature chemistry · 2025Article
- Direct Imaging of Chirality Transfer Induced by Glycosidic Bond Stereochemistry in Carbohydrate Self-Assemblies.Journal of the American Chemical Society · 2025Article
- Regulation of lanthanide supramolecular nanoreactors via a bimetallic cluster cutting strategy to boost aza-Darzens reactions.Nature communications · 2025Article
- Evolution from [ZnChemical science · 2025Article
- Beyond symmetric self-assembly and effective molarity: unlocking functional enzyme mimics with robust organic cages.Beilstein journal of organic chemistry · 2025Article
- Reactivity Inside Molecular Flasks: Acceleration Modes and Types of Selectivity Obtainable.Angewandte Chemie (International ed. in English) · 2024Review
- A Highly Charged Positive Cage Causes Simultaneous Enhancement of Type-II and OSmall science · 2024Article
- Photoswitchable Catalysis by a Self-Assembled Molecular Cage.Journal of the American Chemical Society · 2024Article
- Hierarchically Assembled Gigantic Fe/Co Cyanometallate Clusters Exhibiting Electron Transfer Behavior Above Room Temperature.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Site-selective peptide bond hydrolysis and ligation in water by short peptide-based assemblies.Proceedings of the National Academy of Sciences of the United States of America · 2024Article
- Self-assembled molecular hybrids comprising lacunary polyoxometalates and multidentate imidazole ligands.Chemical science · 2024Article
- Chiral BINOL-phosphate assembled single hexagonal nanotube in aqueous solution for confined rearrangement acceleration.Nature communications · 2024Article
6 more citing papers are in PubMed but not listed here.
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
When an amide group is distorted from its planar conformation, the conjugation between the nitrogen lone pair and the π* orbital of the carbonyl is disrupted and the reactivity towards nucleophiles is enhanced. Although there are several reports on the synthesis of activated twisted amides, amide activation through mechanical twisting is much less common. Here, we report twisted amides that are stabilized through their inclusion in a self-assembled coordination cage. When secondary aromatic amides are included in a T
Identifiers
32313238What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.