ReviewCoordination chemistry reviews2018
Heteroleptic copper phenanthroline complexes in motion: From stand-alone devices to multi-component machinery.
Review in Coordination chemistry reviews, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
8 citing papers in PubMed, 44 citations in OpenAlex.
- Harnessing Dynamic Heteroleptic Complexation for Self-Assembly of Robust Nested Metallo-Supramolecular Cages.Journal of the American Chemical Society · 2025Article
- Steric and Geometrical Frustration Generate Two Higher-Order CuJournal of the American Chemical Society · 2024Article
- Stereocontrolled Self-Assembly of a Helicate-Bridged CuJournal of the American Chemical Society · 2024Article
- Stimuli-Responsive Catenane-Based Catalysts.Angewandte Chemie (International ed. in English) · 2023Article
- Heteroleptic metallosupramolecular aggregatesBeilstein journal of organic chemistry · 2022Review
- Designing narcissistic self-sorting terpyridine moieties with high coordination selectivity for complex metallo-supramolecules.Communications chemistry · 2021Article
- Physicochemical Insight into Coordination Systems Obtained from Copper(II) Bromoacetate and 1,10-Phenanthroline.Molecules (Basel, Switzerland) · 2020Article
- Double Rotors with Fluxional Axles: Domino Rotation and Azide-Alkyne Huisgen Cycloaddition Catalysis.Angewandte Chemie (International ed. in English) · 2020Article
Corrections and comments
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Authors and funding
2 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Two and a half decades of copper phenanthroline-based switches, devices and machines have illustrated the rich dynamic nature of these metal complexes. With an emphasis on the metal-ligand dissociation as the rate-determining step the present review summarizes not only spectacular examples of machinery, but also highlights rate data collected during a variety of investigations. Copper-ligand exchange reactions are mostly triggered by redox processes, addition of metal ions or addition of ligands. While the rate data spread over >8 orders of magnitude, individual effects of solvent, steric bulk, flexibility, σ-basicity and the trajectory (intra- vs. intermolecular dissociation) have large impact. Unfortunately, in many cases the exact mechanism in the rate-determining step (nucleophile-induced vs. monomolecular metal-ligand dissociation) has not been determined, suggesting to invest further efforts in the physical (in)organic chemistry of such coordination-driven systems.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.