ArticleJournal of the American Chemical Society2020
Hypervalent Iodine(III) Compounds as Biaxial Halogen Bond Donors.
Article in Journal of the American Chemical Society, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 23 papers.
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Who cites it
23 citing papers in PubMed.
- Probing Weak Halogen Bonding in Aqueous Solution.Journal of the American Chemical Society · 2026Article
- Structurally Constrained Cyclic (Diacyloxyiodo)Arenes as an Enabling Platform for Hypervalent Iodine(III) Chemistry.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations.Chemical reviews · 2025Review
- Supramolecular assembly of hypervalent iodine macrocycles and alkali metals.Beilstein journal of organic chemistry · 2025Article
- Key-to-lock halogen bond-based tetragonal pyramidal association of iodonium cations with the lacune rims of beta-octamolybdate.Chemical science · 2024Article
- Halogen Bond via an Electrophilic π-Hole on Halogen in Molecules: Does It Exist?International journal of molecular sciences · 2024Article
- Selective recognition and extraction of iodide from pure water by a tripodal selenoimidazol(ium)-based chalcogen bonding receptor.iScience · 2024Article
- A comparison of structure, bonding and non-covalent interactions of aryl halide and diarylhalonium halogen-bond donors.Beilstein journal of organic chemistry · 2024Article
- Halogen Bond-Involving Self-Assembly of Iodonium Carboxylates: Adding a Dimension to Supramolecular Architecture.International journal of molecular sciences · 2023Article
- Cyclic Homo- and Heterohalogen Di-λJournal of the American Chemical Society · 2023Article
- Recent Progress in Cyclic Aryliodonium Chemistry: Syntheses and Applications.Chemical reviews · 2023Review
- Chiral Bromonium Salt (Hypervalent Bromine(III)) withMolecules (Basel, Switzerland) · 2023Article
- Exploring the role of halogen bonding in iodonium ylides: insights into unexpected reactivity and reaction control.Beilstein journal of organic chemistry · 2023Review
- Zwitterionic iodonium species afford halogen bond-based porous organic frameworks.Chemical science · 2022Article
- Stereoselective Synthesis of Cyclobutanes by Contraction of Pyrrolidines.Journal of the American Chemical Society · 2021Article
- Modulating Chalcogen Bonding and Halogen Bonding Sigma-Hole Donor Atom Potency and Selectivity for Halide Anion Recognition.Angewandte Chemie (International ed. in English) · 2021Article
- Trifluorinated Tetralins via I(I)/I(III)-Catalysed Ring Expansion: Programming Conformation by [CHAngewandte Chemie (International ed. in English) · 2021Article
- A Bidentate Iodine(III)-Based Halogen-Bond Donor as a Powerful Organocatalyst*.Angewandte Chemie (International ed. in English) · 2021Article
- Iodonium salts as efficient iodine(iii)-based noncovalent organocatalysts for Knorr-type reactions.RSC advances · 2021Article
- Comparison of Bifurcated Halogen with Hydrogen Bonds.Molecules (Basel, Switzerland) · 2021Article
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
"Hypervalent" iodine(III) derivatives have been established as powerful reagents in organic transformations, but so far only a handful of studies have addressed their potential use as halogen-bonding noncovalent Lewis acids. In contrast to "classical" halogen-bond donors based on iodine(I) compounds, iodine(III) salts feature two directional electrophilic axes perpendicular to each other. Herein we present the first systematic investigation on biaxial binding to such Lewis acids in solution. To this end, hindered and unhindered iodolium species were titrated with various substrates, including diesters and diamides, via
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.