ArticleAngewandte Chemie (International ed. in English)2020
Hydrosulfonylation of Alkenes with Sulfonyl Chlorides under Visible Light Activation.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
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Who cites it
21 citing papers in PubMed, 149 citations in OpenAlex.
- A Proline-Based 'Redox-Release' Platform for Programmed Access to Diverse Sulfur(VI) and Fluoroalkyl Radicals.Research square · 2026Article
- Red Light and Supersilane: A Novel Pathway for Hydrofunctionalizations and Giese Reactions.ACS organic & inorganic Au · 2025Article
- Photoredox/PyridineJournal of the American Chemical Society · 2025Article
- Nickel-catalyzed regiodivergent sulfonylarylation of 1,3-enynes to access allenes and dienes.Chemical science · 2024Article
- An efficient and mild oxidative approach from thiols to sulfonyl derivatives with DMSO/HBr.Chemical science · 2023Article
- One-Pot Synthesis of Sulfonamides from Unactivated Acids and Amines via Aromatic Decarboxylative Halosulfonylation.Journal of the American Chemical Society · 2023Article
- Inexpensive and bench stable diarylmethylium tetrafluoroborates as organocatalysts in the light mediated hydrosulfonylation of unactivated alkenes.Chemical science · 2023Article
- Photo-Induced Halogen-Atom Transfer: Generation of Halide Radicals for Selective Hydrohalogenation Reactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Tricomponent Decarboxysulfonylative Cross-Coupling Facilitates Direct Construction of Aryl Sulfones and Reveals a Mechanistic Dualism in the Acridine/Copper Photocatalytic System.ACS catalysis · 2022Article
- (Hetero)aryl-SAngewandte Chemie (International ed. in English) · 2022Review
- Photocatalytic Late-Stage Functionalization of Sulfonamides via Sulfonyl Radical Intermediates.ACS catalysis · 2022Article
- Functional group divergence and the structural basis of acridine photocatalysis revealed by direct decarboxysulfonylation.Chemical science · 2022Article
- Radical Difunctionalization of Gaseous Ethylene Guided by Quantum Chemical Calculations: Selective Incorporation of Two Molecules of Ethylene.ACS omega · 2021Article
- Recent Progress and Emerging Technologies towards a Sustainable Synthesis of Sulfones.ChemSusChem · 2021Review
- Photoinduced C(spChemical science · 2021Article
- Hydrofluoromethylation of alkenes with fluoroiodomethane and beyond.Chemical science · 2021Article
- Photocatalytic decarboxylative amidosulfonation enables direct transformation of carboxylic acids to sulfonamides.Chemical science · 2021Article
- Divergent reactivity of sulfinates with pyridinium salts based on one-Chemical science · 2021Article
- A Unified Strategy for Arylsulfur(VI) Fluorides from Aryl Halides: Access to Ar-SOFAngewandte Chemie (International ed. in English) · 2020Article
- Organic-photoredox-catalyzed three-component sulfonylative pyridylation of styrenes.RSC advances · 2020Article
Corrections and comments
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Authors and funding
8 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Sulfonyl chlorides are inexpensive reactants extensively explored for functionalization, but never considered for radical hydrosulfonylation of alkenes. Herein, we report that tris(trimethylsilyl)silane is an ideal hydrogen atom donor enabling highly effective photoredox-catalyzed hydrosulfonylation of electron-deficient alkenes with sulfonyl chlorides. To increase the generality of this transformation, polarity-reversal catalysis (PRC) was successfully implemented for alkenes bearing alkyl substituents. This late-stage functionalization method tolerates a remarkably wide range of functional groups, is operationally simple, scalable, and allows access to building blocks which are important for medicinal chemistry and drug discovery.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.