ArticleChemistry (Weinheim an der Bergstrasse, Germany)2020
A Phosphine Functionalized β-Diketimine Ligand for the Synthesis of Manifold Metal Complexes.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed, 24 citations in OpenAlex.
- Modification of a Common β-diketiminate NacNac Framework via Sequential Lithiation and Small Molecule Insertion.Chemistry (Weinheim an der Bergstrasse, Germany) · 2024Article
- Interplay between β-Diimino and β-Diketiminato Ligands in Nickel Complexes Active in the Proton Reduction Reaction.Inorganic chemistry · 2022Article
- The Backbone of Success of P,N-Hybrid Ligands: Some Recent Developments.Molecules (Basel, Switzerland) · 2022Review
- Alkali Metal Complexes of a Bis(diphenylphosphino)methane Functionalized Amidinate Ligand: Synthesis and Luminescence.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Thermally Activated Delayed Fluorescence and Phosphorescence Quenching in Iminophosphonamide Copper and Zinc Complexes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- A Phosphine Functionalized β-Diketimine Ligand for the Synthesis of Manifold Metal Complexes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- A "Push-Pull" Stabilized Phosphinidene Supported by a Phosphine-Functionalized β-Diketiminato Ligand.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
Corrections and comments
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Authors and funding
6 authors at 2 institutions in 2 countries.
Funding
Abstract
A bis(diphenyl)-phosphine functionalized β-diketimine (PNac-H) was synthesized as a flexible ligand for transition metal complexes. The newly designed ligand features symmetrically placed phosphine moieties around a β-diketimine unit, forming a PNNP-type pocket. Due to the hard and soft donor atoms (N vs. P) the ligand can stabilize various coordination polyhedra. A complete series ranging from coordination numbers 2 to 6 was realized. Linear, trigonal planar, square planar, tetrahedral, square pyramidal, and octahedral coordination arrangements containing the PNac-ligand around the metal center were observed by using suitable metal sources. Hereby, PNac-H or its anion PNac
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.