ArticleNature chemistry2020
Intra- and intermolecular self-assembly of a 20-nm-wide supramolecular hexagonal grid.
Article in Nature chemistry, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- Trefoil polymers from a knotted synthon.Nature chemistry · 2026Article
- Novel metallo-supramolecular architectures based on side-pyridine-modified terpyridines: design, self-assembly, and properties.Chemical science · 2025Review
- Exploring diverse supramolecular tessellation through hierarchical assemblies of nonalternant nanographene.Proceedings of the National Academy of Sciences of the United States of America · 2025Article
- Unravelling the Atomic Structure of a Metal-Covalent Organic Framework Assembled from Ruthenium Metalloligands.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- High-order layered self-assembled multicavity metal--organic capsules and anti-cooperative host-multi-guest chemistry.Chemical science · 2024Article
- Giant oligomeric porous cage-based molecules.Chemical science · 2024Article
- Surface-supported metal-organic frameworks with geometric topological diversity via scanning tunneling microscopy.iScience · 2024Review
- Ion Mobility Mass Spectrometry for Large Synthetic Molecules: Expanding the Analytical Toolbox.Journal of the American Chemical Society · 2024Review
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- Monolayer and Bilayer Formation of Molecular 2D Networks Assembled at the Liquid/Solid Interfaces by Solution-Based Drop-Cast Method.Molecules (Basel, Switzerland) · 2021Article
- Designing narcissistic self-sorting terpyridine moieties with high coordination selectivity for complex metallo-supramolecules.Communications chemistry · 2021Article
- Metal atom-guided conformational analysis of single polynuclear coordination molecules.Science advances · 2021Article
- Geometrical manipulation of complex supramolecular tessellations by hierarchical assembly of amphiphilic platinum(II) complexes.Proceedings of the National Academy of Sciences of the United States of America · 2021Article
- Selective Anion Binding Drives the Formation of AgJournal of the American Chemical Society · 2021Article
- On-surface isostructural transformation from a hydrogen-bonded network to a coordination network for tuning the pore size and guest recognition.Chemical science · 2020Article
Corrections and comments
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Authors and funding
16 authors.
Funding
Abstract
For the past three decades, the coordination-driven self-assembly of three-dimensional structures has undergone rapid progress; however, parallel efforts to create large discrete two-dimensional architectures-as opposed to polymers-have met with limited success. The synthesis of metallo-supramolecular systems with well-defined shapes and sizes in the range of 10-100 nm remains challenging. Here we report the construction of a series of giant supramolecular hexagonal grids, with diameters on the order of 20 nm and molecular weights greater than 65 kDa, through a combination of intra- and intermolecular metal-mediated self-assembly steps. The hexagonal intermediates and the resulting self-assembled grid architectures were imaged at submolecular resolution by scanning tunnelling microscopy. Characterization (including by scanning tunnelling spectroscopy) enabled the unambiguous atomic-scale determination of fourteen hexagonal grid isomers.
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