Copper-catalyzed remote C-H arylation of polycyclic aromatic hydrocarbons (PAHs).

Anping Luo, Min Zhang, Zhangyi Fu, Jingbo Lan, Di Wu, Jingsong You

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In one paragraph

Article in Beilstein journal of organic chemistry, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

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1citing papers in PubMed

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1 citing paper in PubMed.

Progress and prospects in copper-catalyzed C-H functionalization.RSC advances · 2020
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Authors and funding

6 authors.

Anping LuoKey Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu 610064, P.R. China.

Min ZhangKey Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu 610064, P.R. China.

Zhangyi FuKey Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu 610064, P.R. China.

Jingbo LanKey Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu 610064, P.R. China.ORCID https://orcid.org/0000-0001-5937-0987

Di WuKey Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu 610064, P.R. China.

Jingsong YouKey Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu 610064, P.R. China.ORCID https://orcid.org/0000-0002-0493-2388

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The regioselective C-H arylation of substituted polycyclic aromatic hydrocarbons (PAHs) is a desired but challenging task. A copper-catalyzed C7-H arylation of 1-naphthamides has been developed by using aryliodonium salts as arylating reagents. This protocol does not need to use precious metal catalysts and tolerates wide variety of functional groups. Under standard conditions, the remote C-H arylation of other PAHs including phenanthrene-9-carboxamide, pyrene-1-carboxamide and fluoranthene-3-carboxamide has also accomplished, which provides an opportunity for the development of diverse organic optoelectronic materials.

Indexed as

C–H arylationcopper catalysisnonprecious metal catalystpolycyclic aromatic hydrocarbons (PAHs)regioselectivity

Identifiers

PMID32280382

DOI10.3762/bjoc.16.49

PMCPMC7136547

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