Evidence map›Paper›PMID 32275144›Full record

ArticleChemical reviews2020

Oxygen K-edge X-ray Absorption Spectra.

Federica Frati, Myrtille O J Y Hunault, Frank M F de Groot

Abstract read
In one paragraph

Article in Chemical reviews, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 127 papers.

0numbers the graph read from it
0cells of the map it votes in
127citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

127 citing papers in PubMed.

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  16. Study on the Reaction Mechanism of RuOAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026
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  20. Article

67 more citing papers are in PubMed but not listed here.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Federica FratiInorganic chemistry and catalysis, Debye Institute for Nanomaterials Science, Utrecht University, 3584CG Utrecht, The Netherlands.
Myrtille O J Y HunaultSynchrotron SOLEIL, L'Orme des Merisiers, Saint Aubin BP 48, 91192 Gif-sur-Yvette, France.ORCID 0000-0002-3754-8630
Frank M F de GrootInorganic chemistry and catalysis, Debye Institute for Nanomaterials Science, Utrecht University, 3584CG Utrecht, The Netherlands.ORCID 0000-0002-1340-2186

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We review oxygen K-edge X-ray absorption spectra of both molecules and solids. We start with an overview of the main experimental aspects of oxygen K-edge X-ray absorption measurements including X-ray sources, monochromators, and detection schemes. Many recent oxygen K-edge studies combine X-ray absorption with time and spatially resolved measurements and/or operando conditions. The main theoretical and conceptual approximations for the simulation of oxygen K-edges are discussed in the Theory section. We subsequently discuss oxygen atoms and ions, binary molecules, water, and larger molecules containing oxygen, including biomolecular systems. The largest part of the review deals with the experimental results for solid oxides, starting from s- and p-electron oxides. Examples of theoretical simulations for these oxides are introduced in order to show how accurate a DFT description can be in the case of s and p electron overlap. We discuss the general analysis of the 3d transition metal oxides including discussions of the crystal field effect and the effects and trends in oxidation state and covalency. In addition to the general concepts, we give a systematic overview of the oxygen K-edges element by element, for the s-, p-, d-, and f-electron systems.

Identifiers

PMID32275144
PMCPMC7227067

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.