ArticleAngewandte Chemie (International ed. in English)2020
A Chemically Soldered Polyoxometalate Single-Molecule Transistor.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Polyoxometalates (POMs) Memristors/Neuromorphic Devices: From Structure Engineering to Material and Function Integration.Nanomaterials (Basel, Switzerland) · 2026Review
- Digging through the (Statistical) Dirt: A Reproducible Method for Single-Molecule Flicker Noise Analysis.The journal of physical chemistry. C, Nanomaterials and interfaces · 2025Article
- Single-Molecule Mechanoresistivity by Intermetallic Bonding.Angewandte Chemie (International ed. in English) · 2025Article
- Nuclear Magnetic Resonance Chemical Shift as a Probe for Single-Molecule Charge Transport.Angewandte Chemie (International ed. in English) · 2024Article
- An Orthogonal Conductance Pathway in Spiropyrans for Well-Defined Electrosteric Switching Single-Molecule Junctions.Small (Weinheim an der Bergstrasse, Germany) · 2024Article
- Article
- Single-Molecule Junction Formation in Deep Eutectic Solvents with Highly Effective Gate Coupling.The journal of physical chemistry. C, Nanomaterials and interfaces · 2023Article
- Design of Pyrrole-Based Gate-Controlled Molecular Junctions Optimized for Single-Molecule Aflatoxin B1 Detection.Sensors (Basel, Switzerland) · 2023Article
- Electrochemically controlled rectification in symmetric single-molecule junctions.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- Redox-Addressable Single-Molecule Junctions Incorporating a Persistent Organic Radical.Angewandte Chemie (International ed. in English) · 2022Article
- Polyoxoplatinates as covalently dynamic electron sponges and molecular electronics materials.Nanoscale advances · 2021Article
- TiOBeilstein journal of nanotechnology · 2021Article
- A Chemically Soldered Polyoxometalate Single-Molecule Transistor.Angewandte Chemie (International ed. in English) · 2020Article
Corrections and comments
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Authors and funding
7 authors.
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Abstract
Polyoxometalates have been proposed in the literature as nanoelectronic components, where they could offer key advantages with their structural versatility and rich electrochemistry. Apart from a few studies on their ensemble behaviour (as monolayers or thin films), this potential remains largely unexplored. We synthesised a pyridyl-capped Anderson-Evans polyoxometalate and used it to fabricate single-molecule junctions, using the organic termini to chemically "solder" a single cluster to two nanoelectrodes. Operating the device in an electrochemical environment allowed us to probe charge transport through different oxidation states of the polyoxometalate, and we report here an efficient three-state transistor behaviour. Conductance data fits a quantum tunnelling mechanism with different charge-transport probabilities through different charge states. Our results show the promise of polyoxometalates in nanoelectronics and give an insight on their single-entity electrochemical behaviour.
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Registered trials
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