ArticleAngewandte Chemie (International ed. in English)2020
Diborane(4) Azides: Surprisingly Stable Sources of Transient Iminoboranes.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Phenylpyridine-Based Boron Azides: Tuning Reactivity and Accessing Fluorescent Triazoles.Inorganic chemistry · 2025Article
- Strain induced reactivity of cyclic iminoboranes: the (2 + 2) cycloaddition of a 1Chemical science · 2024Article
- Diaza-1,3-butadienes as Useful Intermediate in Heterocycles Synthesis.Molecules (Basel, Switzerland) · 2022Review
- A Three-Dimensional Inorganic Analogue of 9,10-Diazido-9,10-Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability.Angewandte Chemie (International ed. in English) · 2022Article
- Bistriazoles Connected Through a B-B Bridge, Synthesized by Highly Selective Dipolar Cycloaddition Reactions of a Diazido-diborane(4).Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Can a Wanzlick-like equilibrium exist between dicoordinate borylenes and diborenes?Chemical science · 2022Article
- Solution Phase Reactivity of Dibenzo[c,e][1,2]azaborinine: Activation and Insertion into Si-E Single Bonds (E=H, OSi(CHChemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Diborane(4) Azides: Surprisingly Stable Sources of Transient Iminoboranes.Angewandte Chemie (International ed. in English) · 2020Article
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7 authors.
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Abstract
Herein we describe the first examples of isolable electron-precise diboranes(4) that bear azide moieties: the acyclic 1,2-diazido-1,2-bis(dimethylamino)diborane(4) and the cyclic 1,4-diaryl-2,3-diazido-1,4-diaza-2,3-diborinines (aryl=mesityl, 2,6-xylyl, 4-tolyl). The reported examples are not only stable enough to be observed and isolated (putative transient diborane(4) azides previously reported by our group spontaneously decompose even below room temperature), but some of them are even robust enough to undergo controlled pyrolysis without explosive decomposition at temperatures well above 100 °C. In two cases, the controlled pyrolysis allows the isolation of complex diazaboretidines, which are the apparent dimerization products of endocyclic boryl-iminoboranes.
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