ArticleAngewandte Chemie (International ed. in English)2020
Synthesis of High χ-Low N Diblock Copolymers by Polymerization-Induced Self-Assembly.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Switchable whiteness in liquid crystal networks via solvent-induced microphase segregation.Nature communications · 2026Article
- Synthesis and Characterization of All-Acrylic Tetrablock Copolymer Nanoparticles: Waterborne Thermoplastic Elastomers via One-Pot RAFT Aqueous Emulsion Polymerization.Chemistry of materials : a publication of the American Chemical Society · 2024Article
- Small-Angle X-Ray Scattering Studies of Block Copolymer Nano-Objects: Formation of Ordered Phases in Concentrated Solution During Polymerization-Induced Self-Assembly.Angewandte Chemie (International ed. in English) · 2021Article
- Construction of Highly Ordered Glyco-Inside Nano-Assemblies through RAFT Dispersion Polymerization of Galactose-Decorated Monomer.Angewandte Chemie (International ed. in English) · 2021Article
- Synthesis of High χ-Low N Diblock Copolymers by Polymerization-Induced Self-Assembly.Angewandte Chemie (International ed. in English) · 2020Article
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Authors and funding
8 authors.
Funding
Abstract
Polymerization-induced self-assembly (PISA) enables the scalable synthesis of functional block copolymer nanoparticles with various morphologies. Herein we exploit this versatile technique to produce so-called "high χ-low N" diblock copolymers that undergo nanoscale phase separation in the solid state to produce sub-10 nm surface features. By varying the degree of polymerization of the stabilizer and core-forming blocks, PISA provides rapid access to a wide range of diblock copolymers, and enables fundamental thermodynamic parameters to be determined. In addition, the pre-organization of copolymer chains within sterically-stabilized nanoparticles that occurs during PISA leads to enhanced phase separation relative to that achieved using solution-cast molecularly-dissolved copolymer chains.
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