ArticleChemistry (Weinheim an der Bergstrasse, Germany)2020
Photoinduced and Thermal Single-Electron Transfer to Generate Radicals from Frustrated Lewis Pairs.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed, 59 citations in OpenAlex.
- From [NHC─H]Angewandte Chemie (International ed. in English) · 2026Article
- Synthesis of zwitterionic open-shell bilayer spironanographenes.Nature chemistry · 2025Article
- Quantifying interactions in the active encounter complex of frustrated Lewis pairs.Nature communications · 2025Article
- Article
- Synthesis and Photochemical Uncaging of Alkene-Protected, Polymer-Bound Vicinal Frustrated Lewis Pairs.Journal of the American Chemical Society · 2024Article
- Mechanistic studies on single-electron transfer in frustrated Lewis pairs and its application to main-group chemistry.Chemical Society reviews · 2024Review
- Single electron reduction of NHC-COChemical science · 2024Article
- Light-Induced Polymeric Frustrated Radical Pairs as Building Blocks for Materials and Photocatalysts.Journal of the American Chemical Society · 2023Article
- Frustrated Radical Pairs in Organic Synthesis.Journal of the American Chemical Society · 2023Review
- Insights into Single-Electron-Transfer Processes in Frustrated Lewis Pair Chemistry and Related Donor-Acceptor Systems in Main Group Chemistry.Chemical reviews · 2023Review
- Article
- Piers' Borane-Induced Tetramerization of Arylacetylenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Phosphorus-Based Catalysis.ACS central science · 2021Review
- Site-Selective CJournal of the American Chemical Society · 2021Article
- Frustrated Radical Pairs: Insights from EPR Spectroscopy.Angewandte Chemie (International ed. in English) · 2021Review
- Single-Electron Transfer in Frustrated Lewis Pair Chemistry.Angewandte Chemie (International ed. in English) · 2020Article
- Long-Lived Charge-Transfer State from B-N Frustrated Lewis Pairs Enchained in Supramolecular Copolymers.Journal of the American Chemical Society · 2020Article
- Photoinduced and Thermal Single-Electron Transfer to Generate Radicals from Frustrated Lewis Pairs.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
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Authors and funding
9 authors at 2 institutions in 2 countries.
Funding
Abstract
Archetypal phosphine/borane frustrated Lewis pairs (FLPs) are famed for their ability to activate small molecules. The mechanism is generally believed to involve two-electron processes. However, the detection of radical intermediates indicates that single-electron transfer (SET) generating frustrated radical pairs could also play an important role. These highly reactive radical species typically have significantly higher energy than the FLP, which prompted this investigation into their formation. Herein, we provide evidence that the classical phosphine/borane combinations PMes
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