ArticleCommunications materials2020
Giant thermal expansion of a two-dimensional supramolecular network triggered by alkyl chain motion.
Article in Communications materials, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
What it found
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Who cites it
10 citing papers in PubMed, 28 citations in OpenAlex.
- Landing-Energy-Controlled Surface Conformation of Electrosprayed Foldamer Molecules on Au(111).ACS nano · 2026Article
- Clean Electrospray Deposition of Porphyrin Molecules and Polyethylene Glycol Chains onto a Au(100) Surface.The journal of physical chemistry. C, Nanomaterials and interfaces · 2026Article
- On-Surface Synthesis and Cryogenic Exfoliation of Sterically Frustrated Atropisomers.ACS nano · 2025Article
- Toward Molecular Textiles: Synthesis and Characterization of Molecular Patches.Chemistry (Weinheim an der Bergstrasse, Germany) · 2024Article
- The Role of Alkyl Chains in the Thermoresponse of Supramolecular Network.Small (Weinheim an der Bergstrasse, Germany) · 2024Article
- Stable Au(111) Hexagonal Reconstruction Induced by Perchlorinated Nanographene Molecules.The journal of physical chemistry. C, Nanomaterials and interfaces · 2024Article
- Solution-Synthesized Extended Graphene Nanoribbons Deposited by High-Vacuum Electrospray Deposition.ACS nano · 2023Article
- Synthesis of Giant Dendritic Polyphenylenes with 366 and 546 Carbon Atoms and Their High-vacuum Electrospray Deposition.Chemistry, an Asian journal · 2022Article
- Reconstruction of a 2D layer of KBr on Ir(111) and electromechanical alteration by graphene.Beilstein journal of nanotechnology · 2021Article
- Influence of electrospray deposition on CBeilstein journal of nanotechnology · 2021Article
Corrections and comments
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Authors and funding
12 authors at 3 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Thermal expansion, the response in shape, area or volume of a solid with heat, is usually large in molecular materials compared to their inorganic counterparts. Resulting from the intrinsic molecule flexibility, conformational changes or variable intermolecular interactions, the exact interplay between these mechanisms is however poorly understood down to the molecular level. Here, we investigate the structural variations of a two-dimensional supramolecular network on Au(111) consisting of shape persistent polyphenylene molecules equipped with peripheral dodecyl chains. By comparing high-resolution scanning probe microscopy and molecular dynamics simulations obtained at 5 and 300 K, we determine the thermal expansion coefficient of the assembly of 980 ± 110 × 10
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.