ArticleBeilstein journal of organic chemistry2020
Room-temperature Pd/Ag direct arylation enabled by a radical pathway.
Article in Beilstein journal of organic chemistry, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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4 citing papers in PubMed.
- Synthetic Method-Defect Correlations in Aldol Polycondensation: From Model Reactions to an n-Type Thiazolothioazole Copolymer.Journal of the American Chemical Society · 2026Article
- Open-flask, ambient temperature direct arylation synthesis of mixed ionic-electronic conductors.Science advances · 2025Article
- Circular Discovery in Small Molecule and Conjugated Polymer Synthetic Methodology.Journal of the American Chemical Society · 2022Article
- Efficient room temperature catalytic synthesis of alternating conjugated copolymers via C-S bond activation.Nature communications · 2022Article
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Abstract
Direct arylation is an appealing method for preparing π-conjugated materials, avoiding the prefunctionalization required for traditional cross-coupling methods. A major effort in organic electronic materials development is improving the environmental and economic impact of production; direct arylation polymerization (DArP) is an effective method to achieve these goals. Room-temperature polymerization would further improve the cost and energy efficiencies required to prepare these materials. Reported herein is new mechanistic work studying the underlying mechanism of room temperature direct arylation between iodobenzene and indole. Results indicate that room-temperature, Pd/Ag-catalyzed direct arylation systems are radical-mediated. This is in contrast to the commonly proposed two-electron mechanisms for direct arylation and appears to extend to other substrates such as benzo[
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