ArticleOrganic letters2020
Site-Selective C-H Functionalization-Sulfination Sequence to Access Aryl Sulfonamides.
Article in Organic letters, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 24 papers.
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Who cites it
24 citing papers in PubMed.
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- Thianthrenium Salts as Aryl Radical Precursors for Direct Arylation of β-Dicarbonyl Compounds via Electrochemical SChemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Late-Stage Functionalization via Thianthrenation: A Reaction Enabling Rapid Preparation of Drug Beads for Chemical Pulldown.Journal of medicinal chemistry · 2026Article
- Catalyst-Free Three-Component Synthesis of 3-Aminoalkyl Chromones Using Rongalite as a C1 Synthon.Molecules (Basel, Switzerland) · 2026Article
- Late-Stage Phenylation From [Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Rongalite addition to dienones: diastereoselectivity in cyclic sulfone synthesis; stereochemical rationalization and prospects as a general conjugate nucleophile.Beilstein journal of organic chemistry · 2026Article
- Site-Selective C-H Sulfinamidation through Electron-Donor-Acceptor Complex Photoactivation and Radical Addition into Sulfinylamine Reagents.Organic letters · 2025Article
- Organothianthrenium salts: synthesis and utilization.Chemical science · 2022Review
- Scalable, Chemoselective Nickel Electrocatalytic Sulfinylation of Aryl Halides with SOAngewandte Chemie (International ed. in English) · 2022Article
- Sustainable Thioetherification via Electron Donor-Acceptor Photoactivation Using Thianthrenium Salts.Angewandte Chemie (International ed. in English) · 2022Article
- Thianthrenium-Enabled Sulfonylation via Electron Donor-Acceptor Complex Photoactivation.Chem catalysis · 2022Article
- Functional group divergence and the structural basis of acridine photocatalysis revealed by direct decarboxysulfonylation.Chemical science · 2022Article
- A Perspective on Late-Stage Aromatic C-H Bond Functionalization.Journal of the American Chemical Society · 2022Article
- Photoinduced C(spChemical science · 2021Article
- Article
- High Site Selectivity in Electrophilic Aromatic Substitutions: Mechanism of C-H Thianthrenation.Journal of the American Chemical Society · 2021Article
- Vinyl Thianthrenium Tetrafluoroborate: A Practical and Versatile Vinylating Reagent Made from Ethylene.Journal of the American Chemical Society · 2021Article
- Modular Synthesis of Alkenyl Sulfamates and β-Ketosulfonamides via Sulfur(VI) Fluoride Exchange (SuFEx) Click Chemistry and Photomediated 1,3-Rearrangement.Organic letters · 2021Article
- Late-Stage Heteroarylation of Hetero(aryl)sulfonium Salts Activated by α-Amino Alkyl Radicals.Angewandte Chemie (International ed. in English) · 2021Article
- Site-Selective C-H alkylation of Complex Arenes by a Two-Step Aryl Thianthrenation-Reductive Alkylation Sequence.Journal of the American Chemical Society · 2021Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Aryl sulfinates are precursors to a diverse number of sulfonyl-derived arenes, which are common motifs in pharmaceuticals and agrochemicals. Here, we report a site-selective two-step C-H sulfination sequence via aryl sulfonium salts to access aryl sulfonamides. Combined with site-selective aromatic thianthrenation, an operationally simple one-pot palladium-catalyzed protocol introduces the sulfonyl group using sodium hydroxymethylsulfinate (Rongalite) as a source of SO
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Registered trials
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