ArticleChemphyschem : a European journal of chemical physics and physical chemistry2020
Through-Space Polar-π Interactions in 2,6-Diarylthiophenols.
Article in Chemphyschem : a European journal of chemical physics and physical chemistry, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Probing Attractive OH-π Interactions and Repulsive n-π Interactions in a Phenol Molecular Balance.Chemistry, an Asian journal · 2026Article
- Probing the Lewis Acidity of Boronic Acids through Interactions with Arene Substituents.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Through-Space Polar-π Interactions in 2,6-Diarylthiophenols.Chemphyschem : a European journal of chemical physics and physical chemistry · 2020Article
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Authors and funding
7 authors.
Funding
Abstract
Molecular recognition between polar groups and aromatic molecules is fundamentally important to rational drug design. Although it has been well established that many polar functionalities interact with electron-rich aromatic residues through energetically favorable polar-π interactions, there is a limited understanding of the association between thiols and aromatic systems. Herein we report physical-organic chemistry studies on 2,6-diarylthiophenols that possess the central thiophenol ring and two flanking aromatic rings with tunable electronic properties caused by substituents at distant para position. Hammett analysis revealed that pK
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Registered trials
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