ArticleAngewandte Chemie (International ed. in English)2020
Enantioselective Pallada-Electrocatalyzed C-H Activation by Transient Directing Groups: Expedient Access to Helicenes.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 55 papers.
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Who cites it
55 citing papers in PubMed.
- Article
- A unified cobalt-electrocatalytic platform for enantio- and stereo-selective C-H and C-F functionalization ofChemical science · 2026Article
- Article
- Construction of remote dual stereocenters by electrochemical cobalt-catalyzed enantioselective desymmetrization.Nature communications · 2026Article
- Tunable enantioselective electrocatalytic functionalization of unactivated alkenes.Nature communications · 2026Article
- Palladium-catalyzed redox diversified entry to axially chiral styrenesChemical science · 2025Article
- AI Approaches to Homogeneous Catalysis with Transition Metal Complexes.ACS catalysis · 2025Review
- Parametrization of κACS catalysis · 2025Article
- Enantioselective electrochemical nickel-catalyzed vinylogous radical reactions.Science advances · 2025Article
- Enantiopure Turbo Chirality Targets in Tri-Propeller Blades: Design, Asymmetric Synthesis, and Computational Analysis.Molecules (Basel, Switzerland) · 2025Article
- Crafting 1,4-diaryl spirobifluorene hosts in OLEDsChemical science · 2024Article
- Electrochemical Enantioselective C-H Annulation by Achiral Rhodium(III)/Chiral Brønsted Base Domino Catalysis.ACS catalysis · 2024Article
- Enantioselective nickel-catalyzed anodic oxidative dienylation and allylation reactions.Nature communications · 2024Article
- Padlocking dihydrofurannulation for the control of small degree of helicity built on a fused-tetracyclic core.Chemical science · 2024Article
- Palladium-Catalyzed Electrooxidative Double C-H Arylation.Journal of the American Chemical Society · 2024Article
- Access to Axially Chiral Aryl Aldehydes via Carbene-Catalyzed Nitrile Formation and Desymmetrization Reaction.Research (Washington, D.C.) · 2024Article
- Cu-catalyzed asymmetric regiodivergent electrosynthesis and its application in the enantioselective total synthesis of (-)-fumimycin.Nature communications · 2023Article
- Enantioselective organocatalytic synthesis of axially chiral aldehyde-containing styrenes via SNature communications · 2023Article
- Cobaltaelectro-Catalyzed C-H Annulation with Allenes for Atropochiral andACS catalysis · 2023Article
- Electrocatalyzed direct arene alkenylations without directing groups for selective late-stage drug diversification.Nature communications · 2023Article
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Authors and funding
6 authors.
Funding
Abstract
Asymmetric pallada-electrocatalyzed C-H olefinations were achieved through the synergistic cooperation with transient directing groups. The electrochemical, atroposelective C-H activations were realized with high position-, diastereo-, and enantio-control under mild reaction conditions to obtain highly enantiomerically-enriched biaryls and fluorinated N-C axially chiral scaffolds. Our strategy provided expedient access to, among others, novel chiral BINOLs, dicarboxylic acids and helicenes of value to asymmetric catalysis. Mechanistic studies by experiments and computation provided key insights into the catalyst's mode of action.
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