ArticleMikrochimica acta2020
Reduced graphene-decorated covalent organic framework as a novel coating for solid-phase microextraction of phthalate esters coupled to gas chromatography-mass spectrometry.
Article in Mikrochimica acta, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Article
- [Recent advances in the use of graphene for sample preparation].Se pu = Chinese journal of chromatography · 2022Article
- [Recent advance of new sample preparation materials in the analysis and detection of environmental pollutants].Se pu = Chinese journal of chromatography · 2021Article
- Covalent Organic Framework Composites: Synthesis and Analytical Applications.Molecules (Basel, Switzerland) · 2020Review
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Authors and funding
3 authors.
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Abstract
Schiff base network-1 (SNW-1), as a new generation of covalent organic frameworks (COFs), was synthesized and modified by fabrication of a composite with graphene oxide (GO). The fabricated nanocomposite was characterized with FT-IR spectroscopy, XRD, FE-SEM, EDX, TGA, and the nitrogen adsorption-desorption technique. Characterization results showed that SNW-1 can reduce GO during the fabrication procedure and produce an effective and stable nanocomposite. This nanocomposite was deposited on the surface of a stainless steel wire via a single phase inversion method with the help of polyethersulfone, as a porous adhesive material. This robust and stable coating was used for head space solid-phase microextraction of phthalate esters (PhEs) from water samples. Determination of the PhEs was performed with gas chromatography coupled to mass spectrometry. SNW-1 is N-rich, and reduced-GO is full of hexagonal conjugated rings. Therefore, due to hydrogen binding and π-interaction, the coating has a high tendency to PhEs. Effective adsorption and desorption parameters were optimized. The performance of the method was evaluated in terms of linear ranges (LRs from 0.05 to 100 μg L
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