ArticleNature communications2020
Supramolecular copolymerization driven by integrative self-sorting of hydrogen-bonded rosettes.
Article in Nature communications, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 29 papers.
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Who cites it
29 citing papers in PubMed.
- Elucidating the Reciprocal Interplay between Supramolecular Polymer Cytoskeletons and Fuel-Dependent Synthetic Cells.Journal of the American Chemical Society · 2026Article
- Curvature-emergent supramolecular polymerization of a porphyrin dyad with a scissor-shaped motif.Chemical science · 2026Article
- Using in-situ small-angle scattering to reveal the structure and dynamics of supramolecular polymers.Nature communications · 2025Review
- Solvent-Triggered Aggregation-Induced Reversal and Enhancement of Circularly Polarized Luminescence in Chiral Salen Metalla-Macrocycles.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Cyclodextrin-Based Pseudocopolymers and Their Biomedical Applications for Drug and Gene Delivery.Small (Weinheim an der Bergstrasse, Germany) · 2025Review
- Homochiral Self-Sorting During Macrocycle Formation and their Chiroptical Properties.ChemistryOpen · 2025Article
- Supramolecular rosette intermediated homochiral double helix.Nature communications · 2025Article
- Multiple hydrogen-bonded dimers: are only the frontier atoms relevant?Physical chemistry chemical physics : PCCP · 2024Article
- Non-destructive real-time monitoring and investigation of the self-assembly process using fluorescent probes.Chemical science · 2024Review
- Supramolecular alternating copolymers with highly efficient fluorescence resonance energy transfer.Chemical science · 2023Article
- Quantification of PEFC Catalyst Layer Saturation via In Silico, Ex Situ, and In Situ Small-Angle X-ray Scattering.ACS applied materials & interfaces · 2023Article
- Hierarchical porous photosensitizers with efficient photooxidation.Nature communications · 2023Article
- Thermoreversible Polymorph Transitions in Supramolecular Polymers of Hydrogen-Bonded Squaramides.Angewandte Chemie (International ed. in English) · 2022Article
- Small-angle X-ray scattering: characterization of cubic Au nanoparticles using Debye's scattering formula.Journal of applied crystallography · 2022Article
- Supramolecular systems chemistry through advanced analytical techniques.Analytical and bioanalytical chemistry · 2022Review
- Enantioselective assembly and recognition of heterochiral porous organic cages deduced from binary chiral components.Chemical science · 2022Article
- Double helical π-aggregate nanoarchitectonics for amplified circularly polarized luminescence.Nature communications · 2022Article
- Tuning Exciton Coupling of Merocyanine Nucleoside Dimers by RNA, DNA and GNA Double Helix Conformations.Angewandte Chemie (International ed. in English) · 2022Article
- Fluorescent supramolecular polymers of barbiturate dyes with thiophene-cored twisted π-systems.Chemical science · 2022Article
- Non-uniform Photoinduced Unfolding of Supramolecular Polymers Leading to Topological Block Nanofibers.Angewandte Chemie (International ed. in English) · 2021Article
Corrections and comments
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Authors and funding
10 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Molecular recognition to preorganize noncovalently polymerizable supramolecular complexes is a characteristic process of natural supramolecular polymers, and such recognition processes allow for dynamic self-alteration, yielding complex polymer systems with extraordinarily high efficiency in their targeted function. We herein show an example of such molecular recognition-controlled kinetic assembly/disassembly processes within artificial supramolecular polymer systems using six-membered hydrogen-bonded supramolecular complexes (rosettes). Electron-rich and poor monomers are prepared that kinetically coassemble through a temperature-controlled protocol into amorphous coaggregates comprising a diverse mixture of rosettes. Over days, the electrostatic interaction between two monomers induces an integrative self-sorting of rosettes. While the electron-rich monomer inherently forms toroidal homopolymers, the additional electrostatic interaction that can also guide rosette association allows helicoidal growth of supramolecular copolymers that are comprised of an alternating array of two monomers. Upon heating, the helicoidal copolymers undergo a catastrophic transition into amorphous coaggregates via entropy-driven randomization of the monomers in the rosette.
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