A Simple Iron-Catalyst for Alkenylation of Ketones Using Primary Alcohols.

Motahar Sk, Ashish Kumar, Jagadish Das, Debasis Banerjee

Abstract read

In one paragraph

Article in Molecules (Basel, Switzerland), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

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2citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

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3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

Earth-Abundant Transition Metals Catalyzed Alkylation, Alkenylation, and Alkynylation of Arenes via Cross Dehydrogenative Coupling (CDC): Synthetic Strategies and Mechanistic Pathways.Topics in current chemistry (Cham) · 2026
Review
Structure-Activity Relationship Studies of Chalcones and Diarylpentanoids with Antitumor Activity: Potency and Selectivity Optimization.Pharmaceuticals (Basel, Switzerland) · 2023
Article

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5 · Who and what money

Authors and funding

4 authors.

Motahar SkDepartment of Chemistry, Laboratory of Catalysis and Organic Synthesis, Indian Institute of Technology Roorkee, Roorkee-247667, India.

Ashish KumarDepartment of Chemistry, Laboratory of Catalysis and Organic Synthesis, Indian Institute of Technology Roorkee, Roorkee-247667, India.

Jagadish DasDepartment of Chemistry, Laboratory of Catalysis and Organic Synthesis, Indian Institute of Technology Roorkee, Roorkee-247667, India.

Debasis BanerjeeDepartment of Chemistry, Laboratory of Catalysis and Organic Synthesis, Indian Institute of Technology Roorkee, Roorkee-247667, India.

Funding

Board of Research in Nuclear Sciences 37(2)/20/33/2016-BRNSDepartment of Science and Technology, Ministry of Science and Technology DST/2018/IF180079

6 · The paper itself

Abstract

Herein, we developed a simple iron-catalyzed system for the α-alkenylation of ketones using primary alcohols. Such acceptor-less dehydrogenative coupling (ADC) of alcohols resulted in the synthesis of a series of important α,β-unsaturated functionalized ketones, having aryl, heteroaryl, alkyl, nitro, nitrile and trifluoro-methyl, as well as halogen moieties, with excellent yields and selectivity. Initial mechanistic studies, including deuterium labeling experiments, determination of rate and order of the reaction, and quantitative determination of H

Indexed as

AlcoholsCatalysisIronKetonesStereoisomerismAlcoholsIronKetonesalcoholsdehydrogenative couplingironsustainabilityα-alkenylation

Identifiers

PMID32235642

DOI10.3390/molecules25071590

PMCPMC7181299

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.