ArticleJournal of the American Chemical Society2020
Umpolung Difunctionalization of Carbonyls via Visible-Light Photoredox Catalytic Radical-Carbanion Relay.
Article in Journal of the American Chemical Society, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
What it found
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Who cites it
21 citing papers in PubMed.
- Geminal Difunctionalizations of Aliphatic Ketones and Aldehydes Enabled by Thioacetal Activation and Deep Electroreduction.Journal of the American Chemical Society · 2026Article
- Photocatalytic reductive carboxylation of unactivated hydrazones with CONature communications · 2026Article
- Deoxygenative Cyanofunctionalization of Aldehydes and Ketones Enabled by Electrochemical Reduction.Journal of the American Chemical Society · 2025Article
- Article
- Hydrocyclization/Defluorination of CFAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Facile Access to Hindered Ethers via Photoinduced O-H Bond Insertions.ACS central science · 2025Article
- Research Progress on the Reaction of Carbon Dioxide with Hydrazones and Their Derivatives.Molecules (Basel, Switzerland) · 2025Review
- Cathodic tandem alkylation/dearomatization of heterocycles enabled by Al-facilitated carbonyl deoxygenation.Nature communications · 2025Article
- Mechanistic Pathways in Cyanide-Mediated Benzoin Condensation: A Comprehensive Electron Localisation Function (ELF) and Catastrophe Theory Analysis of the Umpolung Reaction.Molecules (Basel, Switzerland) · 2025Article
- Metal-free photocatalytic cross-electrophile coupling enables C1 homologation and alkylation of carboxylic acids with aldehydes.Nature communications · 2024Article
- Synthesis of substituted benzylboronates by light promoted homologation of boronic acids withChemical science · 2023Article
- Reshaping aromatic frameworks: expansion of aromatic system drives metallabenzenoids to metallapentalenes.Chemical science · 2023Article
- Photocatalytic Alkylation of C(spAngewandte Chemie (International ed. in English) · 2023Article
- Photo-Induced Homologation of Carbonyl Compounds for Iterative Syntheses.Angewandte Chemie (International ed. in English) · 2022Article
- Umpolung carbonyls enable direct allylation and olefination of carbohydrates.Science advances · 2022Article
- Nickel-Catalyzed Defluorinative Coupling of Aliphatic Aldehydes with Trifluoromethyl Alkenes.ACS catalysis · 2022Article
- Photocatalytic gem-Difluoroolefination Reactions by a Formal C-C Coupling/Defluorination Reaction with Diazoacetates.Angewandte Chemie (International ed. in English) · 2022Article
- Photocatalytic synthesis of tetra-substituted furans promoted by carbon dioxide.Chemical science · 2021Article
- Catalytic Generation of Carbanions through Carbonyl Umpolung.Angewandte Chemie (International ed. in English) · 2021Review
- Stereodivergent synthesis of β-iodoenol carbamates with COChemical science · 2021Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The combination of photoredox catalysis with the Wolff-Kishner (WK) reaction allows the difunctionalization of carbonyl groups by a radical-carbanion relay sequence (photo-Wolff-Kishner reaction). Photoredox initiated radical addition to
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.