ArticleChembiochem : a European journal of chemical biology2020
Metal-Mediated Base Pairing of Rigid and Flexible Benzaldoxime Metallacycles.
Article in Chembiochem : a European journal of chemical biology, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed, 8 citations in OpenAlex.
- Hybridization Probes Featuring a Pyrenylpyridine C-Nucleoside or Its Palladacycle as a Fluorescent Sensor Moiety.Chembiochem : a European journal of chemical biology · 2025Article
- 2-Trifluoromethyl-6-mercurianiline Nucleotide, a SensitiveThe Journal of organic chemistry · 2022Article
- Metal-Mediated Base Pairing of Rigid and Flexible Benzaldoxime Metallacycles.Chembiochem : a European journal of chemical biology · 2020Article
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Authors and funding
3 authors at 1 institution in 1 country.
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Abstract
Oligonucleotides incorporating a central C-nucleoside with either a rigid or flexible benzaldoxime base moiety have been synthesized, and the hybridization properties of their metallacyclic derivatives have been studied by UV melting experiments. In all cases, the metallated duplexes were less stable than their unmetallated counterparts, and the metallacyclic nucleobases did not show a clear preference for any of the canonical nucleobases as a base-pairing partner. With palladated oligonucleotides, increased flexibility translated to less severe destabilization, whereas the opposite was true for the mercurated oligonucleotides; this reflects the greater difficulties in accommodating a rigid Pd
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