ArticleScience advances2020
Isolation of an elusive phosphatetrahedrane.
Article in Science advances, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
10 citing papers in PubMed.
- Kinetically Stable Boron-Heteroatom Bonds.Angewandte Chemie (International ed. in English) · 2026Article
- Isolable f-element diphosphene complexes by phosphinidene group transfer and coupling at uranium.Nature communications · 2025Article
- Structure and photochemistry of di-Chemical science · 2024Article
- Molecular pyramids - from tetrahedranes to [6]pyramidanes.Nature reviews. Chemistry · 2023Review
- Synthesis of phosphiranesChemical science · 2022Article
- Catalytic Synthesis of Cyclopropenium Cations with Rh-Carbynoids.Journal of the American Chemical Society · 2022Article
- Di-tert-butyldiphosphatetrahedrane as a Source of 1,2-Diphosphacyclobutadiene Ligands.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Synthesis of Tetrahedranes Containing the Unique Bridging Hetero-Dipnictogen Ligand EE' (E ≠ E'=P, As, Sb, Bi).Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Activation of Di-tert-butyldiphosphatetrahedrane: Access to (tBuCP)Angewandte Chemie (International ed. in English) · 2021Article
- Unusual Complexes of P(CH)Molecules (Basel, Switzerland) · 2020Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
This exploratory synthesis investigation was undertaken to determine the viability of replacing a single carbon vertex with another p-block element in a highly strained tetrahedrane molecule. Phosphorus was selected for this purpose because the stable molecular form of elemental phosphorus is tetrahedral. Our synthetic strategy was to generate an unsaturated phosphorus center bonded to a substituted cyclopropenyl group, a situation that could lead to closure to provide the desired phosphatetrahedrane framework. This was accomplished by dehydrofluorination of the in situ generated fluorophosphine H(F)P(C
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.