Evidence map›Paper›PMID 32227962›Full record

ArticleOrganic letters2020

Enhanced Synthetic Access to Tris-CF

Pinky Yadav, Sally Khoury, Atif Mahammed, Maryann Morales, Scott C Virgil, Harry B Gray, Zeev Gross

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Organic letters, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Journal of medicinal chemistry · 2023
    Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Pinky YadavSchulich Faculty of Chemistry, Technion Israel Institute of Technology, Haifa 320000, Israel.
Sally KhourySchulich Faculty of Chemistry, Technion Israel Institute of Technology, Haifa 320000, Israel.
Atif MahammedSchulich Faculty of Chemistry, Technion Israel Institute of Technology, Haifa 320000, Israel.
Maryann MoralesDivision of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States.
Scott C VirgilDivision of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States.
Harry B GrayDivision of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States.ORCID 0000-0002-7937-7876
Zeev GrossSchulich Faculty of Chemistry, Technion Israel Institute of Technology, Haifa 320000, Israel.ORCID 0000-0003-1170-2115

Funding

ELECTRON-TRANSFER PROCESSES IN IRON AND COPPER PROTEINSR01DK019038 · NIDDK · CALIFORNIA INSTITUTE OF TECHNOLOGY · PI GRAY, HARRY B, WINKLER, JAY R · 1986 to 2023
$7.0M
NIDDK NIH HHS R01 DK019038
6 · The paper itself

Abstract

Separate focus on the oligomerization and oxidative cyclization steps required for the synthesis of 5,10,15-tris(trifluoromethyl)corrole revealed [bis(trifluoroacetoxy)iodo]benzene (PIFA) as a superior alternative oxidant. Under optimized conditions, the pure free-base corrole was obtained with a 6-fold increase in chemical yield and an 11-fold rise in isolated material per synthesis. The corresponding gallium(III) and manganese(III) complexes were isolated by adding the appropriate metal salt prior to corrole purification.

Indexed as

GalliumManganeseMolecular StructureOrganometallic CompoundsPorphyrinscorroleGalliumManganeseOrganometallic CompoundsPorphyrins

Identifiers

PMID32227962
PMCPMC7187640

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.