ArticleJournal of the American Chemical Society2020
Enantioselective Tail-to-Head Cyclizations Catalyzed by Dual-Hydrogen-Bond Donors.
Article in Journal of the American Chemical Society, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
21 citing papers in PubMed, 62 citations in OpenAlex.
- An anion-binding approach to enantioselective photoredox catalysis.Science (New York, N.Y.) · 2025Article
- The impact of supramolecular self-association of organocatalysts on catalytic performance.Nature reviews. Chemistry · 2025Review
- Selective Noncovalent Catalysis with Small Molecules.Chemical reviews · 2025Review
- Molecular Rotors as Reactivity Probes: Predicting Electrophilicity from the Speed of Rotation.Angewandte Chemie (International ed. in English) · 2025Article
- Reusable Selenenyl Iodide-Initiated Cascade Cyclization of Polyenes with N-terminating Groups.Chemistry, an Asian journal · 2025Article
- Electric-Field Catalysis on Carbon Nanotubes in Electromicrofluidic Reactors: Monoterpene Cyclizations.Angewandte Chemie (International ed. in English) · 2025Article
- Reactivity Inside Molecular Flasks: Acceleration Modes and Types of Selectivity Obtainable.Angewandte Chemie (International ed. in English) · 2024Review
- Development of Enantioselective Lithium-Isothiourea-Boronate-Catalyzed Matteson Homologations.Synlett : accounts and rapid communications in synthetic organic chemistry · 2023Article
- Electrochemical carbon-carbon coupling with enhanced activity and racemate stereoselectivity by microenvironment regulation.Nature communications · 2023Article
- The Origin of Anion-π Autocatalysis.JACS Au · 2023Article
- Anion-π catalysis on carbon allotropes.Beilstein journal of organic chemistry · 2023Review
- Exploring Structure-Function Relationships of Aryl Pyrrolidine-Based Hydrogen-Bond Donors in Asymmetric Catalysis Using Data-Driven Techniques.ACS catalysis · 2022Article
- Enantioselective Tail-to-Head Terpene Cyclizations by Optically Active Hexameric Resorcin[4]arene Capsule Derivatives.Angewandte Chemie (International ed. in English) · 2022Article
- Enantioselective hydrogen-bond-donor catalysis to access diverse stereogenic-at-P(V) compounds.Science (New York, N.Y.) · 2022Article
- Resolving Oxygenation Pathways in Manganese-Catalyzed C(spJournal of the American Chemical Society · 2022Article
- Programmed Polyene Cyclization Enabled by Chromophore Disruption.Journal of the American Chemical Society · 2022Article
- Enantioselective catalytic 1,2-boronate rearrangements.Science (New York, N.Y.) · 2021Article
- Bioinspired Ether Cyclizations within a π-Basic Capsule Compared to Autocatalysis on π-Acidic Surfaces and Pnictogen-Bonding Catalysts.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- A Case Study in Catalyst Generality: Simultaneous, Highly-Enantioselective Brønsted- and Lewis-Acid Mechanisms in Hydrogen-Bond-Donor Catalyzed Oxetane Openings.Journal of the American Chemical Society · 2021Article
- Halides as versatile anions in asymmetric anion-binding organocatalysis.Beilstein journal of organic chemistry · 2021Review
Corrections and comments
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
Abstract
Chiral urea derivatives are shown to catalyze enantioselective tail-to-head cyclization reactions of neryl chloride analogues. Experimental data are consistent with a mechanism in which π-participation by the nucleophilic olefin facilitates chloride ionization and thereby circumvents simple elimination pathways. Kinetic and computational studies support a cooperative mode of catalysis wherein two molecules of the urea catalyst engage the substrate and induce enantioselectivity through selective transition state stabilization.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.