ArticleNature communications2020
δ and φ back-donation in An
Article in Nature communications, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
21 citing papers in PubMed.
- Hydrogen-Induced, Unexpectedly Strong 8c-2e ϕ Bond in AnJACS Au · 2026Article
- Reactivity Studies on the Terminal Thorium Imido Metallocene (ηInorganic chemistry · 2026Article
- Electronic Structure, Ligand Effects, and Chemical Reactivity of the Ground and Low-Lying Excited Electronic States of NpOMolecules (Basel, Switzerland) · 2026Article
- Aromaticity in Ancient Zeise's Salt.Inorganic chemistry · 2025Article
- Synthesis and Reactivity of Lewis-Base-Supported Terminal Thorium Imido Metallocene, (ηInorganic chemistry · 2025Article
- Computational Investigation of the Chemical Bond between An(III) Ions and Soft-Donor Ligands.Inorganic chemistry · 2025Article
- MLTB: Enhancing Transferability and Extensibility of Density Functional Tight-Binding Theory with Many-body Interaction Corrections.Journal of chemical theory and computation · 2025Article
- Theoretical Investigation on One-Electron ϕ···ϕ Bonding in Diuranium Inverse Sandwich UInorganic chemistry · 2024Article
- Proton-Coupled Electron Transfer at the PuJournal of the American Chemical Society · 2024Article
- Alkyl Coordination inOrganometallics · 2024Article
- What is the nature of the uranium(iii)-arene bond?Chemical science · 2024Article
- Synthesis and comparison of iso-structural f-block metal complexes (Ce, U, Np, Pu) featuringChemical science · 2023Article
- A Comprehensive Study Concerning the Synthesis, Structure, and Reactivity of Terminal Uranium Oxido, Sulfido, and Selenido Metallocenes.Journal of the American Chemical Society · 2023Article
- Isolation of dissolved organic matter from aqueous solution by precipitation with FeClScientific reports · 2023Article
- An Allyl Uranium(IV) Sandwich Complex: Are ϕ Bonding Interactions Possible?Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Uranium: The Nuclear Fuel Cycle and Beyond.International journal of molecular sciences · 2022Review
- Actinide arene-metalates: ion pairing effects on the electronic structure of unsupported uranium-arenide sandwich complexes.Chemical science · 2021Article
- Uranium versus Thorium: Synthesis and Reactivity of [ηChemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Experimental and Computational Studies on a Base-Free Terminal Uranium Phosphinidene Metallocene.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Distinct electronic structures and bonding interactions in inverse-sandwich samarium and ytterbium biphenyl complexes.Chemical science · 2020Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
In all known examples of metal-ligand (M-L) δ and φ bonds, the metal orbitals are aligned to the ligand orbitals in a "head-to-head" or "side-to-head" fashion. Here, we report two fundamentally new types of M-L δ and φ interactions; "head-to-side" δ and "side-to-side" φ back-bonding, found in complexes of metallacyclopropenes and metallacyclocumulenes of actinides (Pa-Pu) that makes them distinct from their corresponding Group 4 analogues. In addition to the known Th and U complexes, our calculations include complexes of Pa, Np, and Pu. In contrast with conventional An-C bond decreasing, due to the actinide contraction, the An-C distance increases from Pa to Pu. We demonstrate that the direct L-An σ and π donations combined with the An-L δ or φ back-donations are crucial in explaining this non-classical trend of the An-L bond lengths in both series, underscoring the significance of these δ/φ back-donation interactions, and their importance for complexes of Pa and U in particular.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.