ArticleNature nanotechnology2020
Charge disproportionate molecular redox for discrete memristive and memcapacitive switching.
Article in Nature nanotechnology, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed, 108 citations in OpenAlex.
- Molecular Design Toward High-Performance Solution-Processable Push-Pull Zinc(II) Porphyrin-Based Resistive Memory Devices: From Binary to Ternary Memory Behavior.Small science · 2026Article
- Origin of Stabilization of Ligand-Centered Mixed Valence Ruthenium Azopyridine Complexes: DFT Insights for Neuromorphic Applications.The journal of physical chemistry letters · 2025Article
- Electric Field-Driven Conformational Changes in Molecular Memristor and Synaptic Behavior.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Molecular HDD logic for encrypted massive data storage.Nature communications · 2025Article
- Potential and challenges of computing with molecular materials.Nature materials · 2024Review
- Article
- Gradual Change between Coherent and Incoherent Tunneling Regimes Induced by Polarizable Halide Substituents in Molecular Tunnel Junctions.Journal of the American Chemical Society · 2024Article
- Memristor-based adaptive neuromorphic perception in unstructured environments.Nature communications · 2024Article
- Approaching the Zero-Power Operating Limit in a Self-Coordinated Organic Protonic Synapse.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
- An ultrasmall organic synapse for neuromorphic computing.Nature communications · 2023Article
- An artificial synapse based on molecular junctions.Nature communications · 2023Article
- Advances of Various Heterogeneous Structure Types in Molecular Junction Systems and Their Charge Transport Properties.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Review
- Decision trees within a molecular memristor.Nature · 2021Article
- Influence of the Contact Geometry and Counterions on the Current Flow and Charge Transfer in Polyoxometalate Molecular Junctions: A Density Functional Theory Study.The journal of physical chemistry. C, Nanomaterials and interfaces · 2021Article
- Size-selective Pt siderophores based on redox active azo-aromatic ligands.Chemical science · 2020Article
Corrections and comments
- Erratum issued
Authors and funding
14 authors at 6 institutions in 6 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Electronic symmetry breaking by charge disproportionation results in multifaceted changes in the electronic, magnetic and optical properties of a material, triggering ferroelectricity, metal/insulator transition and colossal magnetoresistance. Yet, charge disproportionation lacks technological relevance because it occurs only under specific physical conditions of high or low temperature or high pressure. Here we demonstrate a voltage-triggered charge disproportionation in thin molecular films of a metal-organic complex occurring in ambient conditions. This provides a technologically relevant molecular route for simultaneous realization of a ternary memristor and a binary memcapacitor, scalable down to a device area of 60 nm
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Registered trials
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