ArticleChemical science2020
Carbene metal amide photoemitters: tailoring conformationally flexible amides for full color range emissions including white-emitting OLED.
Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
18 citing papers in PubMed.
- Substituent-controlled donor binding and local reactivity in N-heterocyclic carbene copper amide complexes: a DFT study.Journal of molecular modeling · 2026Article
- Organophosphides: A New Class of Luminophore Ligands for Copper(I) Carbene Based TADF Emitters and Photocatalysts.Angewandte Chemie (International ed. in English) · 2026Article
- Zincafluorene complex with an empty C-Zn π orbital that captures visible light.Chemical science · 2026Article
- Capturing the short-lived excited singlet state in crystals of a TADF silver(I) complex.Chemical communications (Cambridge, England) · 2025Article
- Dye Induced Luminescence Properties of Gold(I) Complexes with near Unity Quantum Efficiency.Angewandte Chemie (International ed. in English) · 2025Article
- The Golden Age of Thermally Activated Delayed Fluorescence Materials: Design and Exploitation.Chemical reviews · 2024Review
- Luminescent carbene-copper(i)-amide polymers for efficient host-free solution-processed OLEDs.Chemical science · 2024Article
- Achieving Long-Wavelength Electroluminescence Using Two-Coordinate Gold(I) Complexes: Overcoming the Energy Gap Law.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Tailoring Carbene-Metal-Amides for Thermally Activated Delayed Fluorescence: A Computationally Guided Study on the Effect of Cyclic (Alkyl)(amino)carbenes.Molecules (Basel, Switzerland) · 2023Article
- Donor, Acceptor, and Molecular Charge Transfer Emission All in One Molecule.The journal of physical chemistry letters · 2023Article
- Excited-State Lifetime Modulation by Twisted and Tilted Molecular Design in Carbene-Metal-Amide Photoemitters.Chemistry of materials : a publication of the American Chemical Society · 2022Article
- Synthesis and photophysical properties of linear gold(I) complexes based on a CCC carbene.Dalton transactions (Cambridge, England : 2003) · 2021Article
- Fabrication of a Solution-Processed White Light Emitting Diode Containing a Single Dimeric Copper(I) Emitter Featuring Combined TADF and Phosphorescence.Micromachines · 2021Article
- Simple Synthetic Routes to Carbene-M-Amido (M=Cu, Ag, Au) Complexes for Luminescence and Photocatalysis Applications.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- P∩N Bridged Cu(I) Dimers Featuring Both TADF and Phosphorescence. From Overview towards Detailed Case Study of the Excited Singlet and Triplet States.Molecules (Basel, Switzerland) · 2021Article
- The Critical Role of nπ* States in the Photophysics and Thermally Activated Delayed Fluorescence of Spiro Acridine-Anthracenone.The journal of physical chemistry letters · 2021Article
- Thermally Activated Delayed Fluorescence from dChemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Excited State Dynamics of Thermally Activated Delayed Fluorescence from an Excited State Intramolecular Proton Transfer System.The journal of physical chemistry letters · 2020Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
12 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Conformationally flexible "Carbene-Metal-Amide" (CMA) complexes of copper and gold have been developed based on a combination of sterically hindered cyclic (alkyl)(amino)carbene (CAAC) and 6- and 7-ring heterocyclic amide ligands. These complexes show photoemissions across the visible spectrum with PL quantum yields of up to 89% in solution and 83% in host-guest films. Single crystal X-ray diffraction and photoluminescence (PL) studies combined with DFT calculations indicate the important role of ring structure and conformational flexibility of the amide ligands. Time-resolved PL shows efficient delayed emission with sub-microsecond to microsecond excited state lifetimes at room temperature, with radiative rates exceeding 10
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.