Evidence map›Paper›PMID 32190251›Full record

ArticleChemical science2019

Ni-catalyzed 1,2-benzylboration of 1,2-disubstituted unactivated alkenes.

Seewon Joung, Allison M Bergmann, M Kevin Brown

Abstract read
In one paragraph

Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed.

  1. Direct Carboboration of Aryl Alkenes with Stable Organoborons Through Ziegler-Type Addition.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025
    Article
  2. Article
  3. Cyclization by Intramolecular Suzuki-Miyaura Cross-Coupling-A Review.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025
    Review
  4. Article
  5. Article
  6. Construction of congested CspChemical science · 2021
    Article
  7. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Seewon JoungIndiana University , Department of Chemistry , 800 E. Kirkwood Ave , Bloomington , IN 47405 , USA . Email: brownmkb@indiana.edu.ORCID 0000-0002-6989-444X
Allison M BergmannIndiana University , Department of Chemistry , 800 E. Kirkwood Ave , Bloomington , IN 47405 , USA . Email: brownmkb@indiana.edu.
M Kevin BrownIndiana University , Department of Chemistry , 800 E. Kirkwood Ave , Bloomington , IN 47405 , USA . Email: brownmkb@indiana.edu.ORCID 0000-0002-4993-0917

Funding

Methods and Strategies for Chemical SynthesisR35GM131755 · NIGMS · TRUSTEES OF INDIANA UNIVERSITY · PI Michael Kevin Brown · 2019 to 2026
$4.0M
Development of New Catalytic Reactions for Chemical SynthesisR01GM114443 · NIGMS · TRUSTEES OF INDIANA UNIVERSITY · PI BROWN, MICHAEL KEVIN · 2015 to 2019
$1.4M
NIGMS NIH HHS R01 GM114443NIGMS NIH HHS R35 GM131755
6 · The paper itself

Abstract

Nickel-catalyzed 1,2-carboboration of alkenes is emerging as a useful method for chemical synthesis. Prior studies have been limited to only the incorporation of aryl groups. In this manuscript, a method for the 1,2-benzylboration of unactivated alkenes is presented. The reaction combines readily available alkenes, diboron reagents and benzylchlorides to generate synthetically versatile products with control of stereochemistry. The utility of the products as well as the mechanistic details of the process are also presented.

Identifiers

PMID32190251
PMCPMC7066668

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.