ArticleAngewandte Chemie (International ed. in English)2020
The "Green" Electrochemical Synthesis of Periodate.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
17 citing papers in PubMed.
- Redox chemistry, catalysis, and electrochemical detection of periodate species: sensors, mechanisms, and applications in green chemistry.Frontiers in chemistry · 2026Review
- Hectogram-Scale Synthesis of Carbamates Using Electrochemical Hofmann Rearrangement in Flow.Organic process research & development · 2025Article
- Highly Concentrated Peroxodicarbonate for Efficient Oxidative Degradation of Kraft Lignin.ChemSusChem · 2025Article
- Beyond Traditional Synthesis: Electrochemical Approaches to Amine Oxidation for Nitriles and Imines.ACS organic & inorganic Au · 2024Review
- Pilot Scale Electrolysis of Peroxodicarbonate as an Oxidizer for Lignin Valorization.ACS sustainable chemistry & engineering · 2024Article
- Formation of substituted dioxanes in the oxidation of gum arabic with periodate.Green chemistry : an international journal and green chemistry resource : GC · 2023Article
- Reductive Amination of Dialdehyde Cellulose: Access to Renewable Thermoplastics.Biomacromolecules · 2023Article
- Aqueous synthesis of highly functional, hydrophobic, and chemically recyclable cellulose nanomaterials through oxime ligation.Nature communications · 2022Article
- Robust and Self-Cleaning Electrochemical Production of Periodate.ChemSusChem · 2022Article
- Concentrated Aqueous Peroxodicarbonate: Efficient Electrosyn- thesis and Use as Oxidizer in Epoxidations, S-, and N-Oxidations.Angewandte Chemie (International ed. in English) · 2022Article
- Working at the interfaces of data science and synthetic electrochemistry.Tetrahedron chem · 2022Article
- Article
- Anodic Dehydrogenative Cyanamidation of Thioethers: Simple and Sustainable Synthesis of N-Cyanosulfilimines.Angewandte Chemie (International ed. in English) · 2021Article
- Electrocatalysis as an enabling technology for organic synthesis.Chemical Society reviews · 2021Article
- Electrocatalytic Activation of Donor-Acceptor Cyclopropanes and Cyclobutanes: An Alternative C(spAngewandte Chemie (International ed. in English) · 2021Article
- Electro-organic synthesis - a 21Chemical science · 2020Review
- The "Green" Electrochemical Synthesis of Periodate.Angewandte Chemie (International ed. in English) · 2020Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
High-grade periodate is relatively expensive, but is required for many sensitive applications such as the synthesis of active pharmaceutical ingredients. These high costs originate from using lead dioxide anodes in contemporary electrochemical methods and from expensive starting materials. A direct and cost-efficient electrochemical synthesis of periodate from iodide, which is less costly and relies on a readily available starting material, is reported. The oxidation is conducted at boron-doped diamond anodes, which are durable, metal-free, and nontoxic. The avoidance of lead dioxide ultimately lowers the cost of purification and quality assurance. The electrolytic process was optimized by statistical methods and was scaled up in an electrolysis flow cell that enhanced the space-time yields by a cyclization protocol. An LC-PDA analytical protocol was established enabling simple quantification of iodide, iodate, and periodate simultaneously with remarkable precision.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.