ArticleNature communications2020
Dichloromethylation of enones by carbon nitride photocatalysis.
Article in Nature communications, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
What it found
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Who cites it
22 citing papers in PubMed.
- Calorimetry informed visual digital model for continuous flow photobromination.Communications chemistry · 2026Article
- Proline-promoted electrophilic dichloromethylation of α-enaminones via stereochemically gated resolution.Nature communications · 2026Article
- Sustainable and Scalable Flow Photochemical Conversions Using a Labile Ligand-Assembled Iron Complex.JACS Au · 2026Article
- Organic Synthesis Mediated by Carbon Nitride Photocatalysis and Photocharged Carbon Nitrides.Accounts of chemical research · 2026Article
- Engineering Polyheptazine and Polytriazine Imides for Photocatalysis.Angewandte Chemie (International ed. in English) · 2024Review
- Photoinduced Zn-Air Battery-Assisted Self-Powered Sensor Utilizing Cobalt and Sulfur Co-Doped Carbon Nitride for Portable Detection Device.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Diastereoselective dearomatization of indoles via photocatalytic hydroboration on hydramine-functionalized carbon nitride.Nature communications · 2024Article
- Heterogeneous Organocatalysts for Light-Driven Reactions in Continuous Flow.Molecules (Basel, Switzerland) · 2024Review
- Extent of carbon nitride photocharging controls energetics of hydrogen transfer in photochemical cascade processes.Nature communications · 2023Article
- Polymeric Carbon Nitrides for Photoelectrochemical Applications: Ring Opening-Induced Degradation.Nanomaterials (Basel, Switzerland) · 2023Article
- Coupling photocatalytic water oxidation with reductive transformations of organic molecules.Nature communications · 2022Article
- Photocatalytic cyclization of nitrogen-centered radicals with carbon nitride through promoting substrate/catalyst interaction.Nature communications · 2022Article
- Boron-Promoted Deprotonative Conjugate Addition: Geminal Diborons as Soft Pronucleophiles and Acyl Anion Equivalents.The Journal of organic chemistry · 2022Article
- Identification of the Structure of Triethanolamine Oxygenation Products in Carbon Nitride Photocatalysis.ChemistryOpen · 2022Article
- In Situ Analyses of Surface-Layer Composition of CxNy Thin Films Using Methods Based on Penning Ionization Processes-Introductory Investigations.Materials (Basel, Switzerland) · 2021Article
- Multisite PCET with photocharged carbon nitride in dark.Exploration (Beijing, China) · 2021Article
- Sol-Gel Processing of Water-Soluble Carbon Nitride Enables High-Performance Photoanodes*.ChemSusChem · 2021Article
- Enhanced Organic Photocatalysis in Confined Flow through a Carbon Nitride Nanotube Membrane with Conversions in the Millisecond Regime.ACS nano · 2021Article
- Metal-Free Photocatalysis: Two-Dimensional Nanomaterial Connection toward Advanced Organic Synthesis.ACS nano · 2021Article
- Unconventional Photocatalysis in Conductive Polymers: Reversible Modulation of PEDOT:PSS Conductivity by Long-Lived Poly(Heptazine Imide) Radicals.Angewandte Chemie (International ed. in English) · 2021Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
Small organic radicals are ubiquitous intermediates in photocatalysis and are used in organic synthesis to install functional groups and to tune electronic properties and pharmacokinetic parameters of the final molecule. Development of new methods to generate small organic radicals with added functionality can further extend the utility of photocatalysis for synthetic needs. Herein, we present a method to generate dichloromethyl radicals from chloroform using a heterogeneous potassium poly(heptazine imide) (K-PHI) photocatalyst under visible light irradiation for C1-extension of the enone backbone. The method is applied on 15 enones, with γ,γ-dichloroketones yields of 18-89%. Due to negative zeta-potential (-40 mV) and small particle size (100 nm) K-PHI suspension is used in quasi-homogeneous flow-photoreactor increasing the productivity by 19 times compared to the batch approach. The resulting γ,γ-dichloroketones, are used as bifunctional building blocks to access value-added organic compounds such as substituted furans and pyrroles.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.