ArticleAngewandte Chemie (International ed. in English)2020
A Transannular Polyene Tetracyclization for Rapid Construction of the Pimarane Framework.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
7 citing papers in PubMed.
- A Divergent Polyene Cyclization for the Total Synthesis of Greenwayodendrines, Greenwaylactams, Polysin and Polyveoline.Angewandte Chemie (International ed. in English) · 2023Article
- Alcohols as Efficient Intermolecular Initiators for a Highly Stereoselective Polyene Cyclisation Cascade.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Short, Divergent, and Enantioselective Total Synthesis of BioactiveOrganic letters · 2022Article
- A Synthetic View on Momilactones and Related 9Frontiers in chemistry · 2022Review
- Bifunctional Polyene Cyclizations: Synthetic Studies on Pimarane Natural Products.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Beyond the Isoprene Pattern: Bifunctional Polyene Cyclizations.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- A Transannular Polyene Tetracyclization for Rapid Construction of the Pimarane Framework.Angewandte Chemie (International ed. in English) · 2020Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Polyene cyclizations are one of the most powerful and fascinating chemical transformations to rapidly generate molecular complexity. However, cyclizations employing heteroatom-substituted polyenes are rare. Described here is the tetracyclization of a dual nucleophilic aryl enol ether involving an unprecedented transannular endo-termination step. In this transformation, five stereocenters, two of which are quaternary, four carbon-carbon bonds, and four six-membered rings are formed from a readily available cyclization precursor. The realization of this cyclization enabled short synthetic access to the tricyclic diterpenoid pimara-15-en-3α-8α-diol.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.