Evidence map›Paper›PMID 32165626›Full record

ArticleNature communications2020

Quantum dissipation driven by electron transfer within a single molecule investigated with atomic force microscopy.

Jan Berger, Martin Ondráček, Oleksandr Stetsovych, Pavel Malý, Petr Holý, Jiří Rybáček, Martin Švec, Irena G Stará, Tomáš Mančal, Ivo Starý and 1 more

Abstract read
In one paragraph

Article in Nature communications, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
  4. Article
  5. Article
  6. Article
  7. Article
  8. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Jan Berger *Institute of Physics of the Czech Academy of Sciences, Cukrovarnická 10, 16200, Prague 6, Czech Republic.
Martin Ondráček *Institute of Physics of the Czech Academy of Sciences, Cukrovarnická 10, 16200, Prague 6, Czech Republic.ORCID http://orcid.org/0000-0002-8808-1487
Oleksandr Stetsovych *Institute of Physics of the Czech Academy of Sciences, Cukrovarnická 10, 16200, Prague 6, Czech Republic.
Pavel MalýCharles University, Faculty of Mathematics and Physics, Ke Karlovu 5, 121 16, Prague 2, Czech Republic.
Petr HolýInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 2, 16610, Prague 6, Czech Republic.
Jiří RybáčekInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 2, 16610, Prague 6, Czech Republic.
Martin ŠvecInstitute of Physics of the Czech Academy of Sciences, Cukrovarnická 10, 16200, Prague 6, Czech Republic.
Irena G StaráInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 2, 16610, Prague 6, Czech Republic.ORCID http://orcid.org/0000-0002-5267-9604
Tomáš MančalCharles University, Faculty of Mathematics and Physics, Ke Karlovu 5, 121 16, Prague 2, Czech Republic.ORCID http://orcid.org/0000-0003-1736-3054
Ivo StarýInstitute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 2, 16610, Prague 6, Czech Republic.
Pavel JelínekInstitute of Physics of the Czech Academy of Sciences, Cukrovarnická 10, 16200, Prague 6, Czech Republic. jelinekp@fzu.cz.ORCID http://orcid.org/0000-0002-5645-8542

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Intramolecular charge transfer processes play an important role in many biological, chemical and physical processes including photosynthesis, redox chemical reactions and electron transfer in molecular electronics. These charge transfer processes are frequently influenced by the dynamics of their molecular or atomic environments, and they are accompanied with energy dissipation into this environment. The detailed understanding of such processes is fundamental for their control and possible exploitation in future technological applications. Most of the experimental studies of the intramolecular charge transfer processes so far have been carried out using time-resolved optical spectroscopies on large molecular ensembles. This hampers detailed understanding of the charge transfer on the single molecular level. Here we build upon the recent progress in scanning probe microscopy, and demonstrate the control of mixed valence state. We report observation of single electron transfer between two ferrocene redox centers within a single molecule and the detection of energy dissipation associated with the single electron transfer.

Identifiers

PMID32165626
PMCPMC7067884

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.