Evidence map›Paper›PMID 32154630›Full record

ReviewAngewandte Chemie (International ed. in English)2020

Principles of Aggregation-Induced Emission: Design of Deactivation Pathways for Advanced AIEgens and Applications.

Satoshi Suzuki, Shunsuke Sasaki, Amir Sharidan Sairi, Riki Iwai, Ben Zhong Tang, Gen-Ichi Konishi

Abstract readReview
In one paragraph

Review in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 49 papers.

0numbers the graph read from it
0cells of the map it votes in
49citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

49 citing papers in PubMed.

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  6. Deciphering Design of Aggregation-Induced Emission Materials by Data Interpretation.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Satoshi SuzukiFukui Institute for Fundamental Chemistry, Kyoto University, Takano-Nishibiraki-cho 34-4, Sakyou-ku, Kyoto, 606-8103, Japan.ORCID http://orcid.org/0000-0001-8358-1629
Shunsuke SasakiUniversité de Nantes, CNRS, Institut des Matériaux Jean Rouxel, IMN, F-44000, Nantes, France.
Amir Sharidan SairiDepartment of Chemical Science and Engineering, Tokyo Institute of Technology, 2-12-1-H-134 O-okayama, Meguro-ku, Tokyo, 152-8552, Japan.
Riki IwaiDepartment of Chemical Science and Engineering, Tokyo Institute of Technology, 2-12-1-H-134 O-okayama, Meguro-ku, Tokyo, 152-8552, Japan.
Ben Zhong TangDepartment of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong.ORCID http://orcid.org/0000-0002-0293-964X
Gen-Ichi KonishiDepartment of Chemical Science and Engineering, Tokyo Institute of Technology, 2-12-1-H-134 O-okayama, Meguro-ku, Tokyo, 152-8552, Japan.ORCID http://orcid.org/0000-0002-6322-0364

Funding

Japan Science and Technology Agency PRESTO (New Materials Science and Element Strategy)Japan Society for the Promotion of Science Grant-in-Aid for JSPS Fellows 16J10324Japan Society for the Promotion of Science Grant-in-Aid for Scientific Research (B) 18H02045Japan Society for the Promotion of Science Grant-in-Aid for Scientific Research on Innovative Areas 17H05145Japan Society for the Promotion of Science JSPS Overseas Research Fellowships
6 · The paper itself

Abstract

Twenty years ago, the concept of aggregation-induced emission (AIE) was proposed, and this unique luminescent property has attracted scientific interest ever since. However, AIE denominates only the phenomenon, while the details of its underlying guiding principles remain to be elucidated. This minireview discusses the basic principles of AIE based on our previous mechanistic study of the photophysical behavior of 9,10-bis(N,N-dialkylamino)anthracene (BDAA) and the corresponding mechanistic analysis by quantum chemical calculations. BDAA comprises an anthracene core and small electron donors, which allows the quantum chemical aspects of AIE to be discussed. The key factor for AIE is the control over the non-radiative decay (deactivation) pathway, which can be visualized by considering the conical intersection (CI) on a potential energy surface. Controlling the conical intersection (CI) on the potential energy surface enables the separate formation of fluorescent (CI:high) and non-fluorescent (CI:low) molecules [control of conical intersection accessibility (CCIA)]. The novelty and originality of AIE in the field of photochemistry lies in the creation of functionality by design and in the active control over deactivation pathways. Moreover, we provide a new design strategy for AIE luminogens (AIEgens) and discuss selected examples.

Indexed as

aggregation-induced emissionbis(dialkylamino)anthracenecontrol of conical intersection accessibility

Identifiers

PMID32154630
PMCPMC7318703

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.