ArticleAngewandte Chemie (International ed. in English)2020
Insights into Cobalta(III/IV/II)-Electrocatalysis: Oxidation-Induced Reductive Elimination for Twofold C-H Activation.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
What it found
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Who cites it
20 citing papers in PubMed.
- 3d Transition Metals-Catalyzed Electrooxidative and Photoredox Asymmetric CH Activation: A Sustainable Futuristic Prospective.Chemical record (New York, N.Y.) · 2026Review
- Asymmetric Catalysis: Recent Advances toward a More Sustainable Synthesis.ACS central science · 2026Review
- Review
- Unlocking Catalysis Using Oxidatively Induced Reductive Elimination.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Review
- Parametrization of κACS catalysis · 2025Article
- Mechanistic Investigations of Cobalt-Catalyzed, Aminoquinoline-Directed C(spJournal of the American Chemical Society · 2025Article
- Enantioselective Cobaltaphotoredox-Catalyzed C-H Activation.Journal of the American Chemical Society · 2024Article
- Cobaltaelectro-Catalyzed C-H Annulation with Allenes for Atropochiral andACS catalysis · 2023Article
- Electro-Synthesis of Organic Compounds with Heterogeneous Catalysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022Review
- Distal Ruthenaelectro-Catalyzed meta-C-H Bromination with Aqueous HBr.Angewandte Chemie (International ed. in English) · 2022Article
- Rhodaelectro-Catalyzed peri-Selective Direct Alkenylations with Weak O-Coordination Enabled by the Hydrogen Evolution Reaction (HER).Angewandte Chemie (International ed. in English) · 2022Article
- Rhoda-Electrocatalyzed Bimetallic C-H Oxygenation by Weak O-Coordination.Angewandte Chemie (International ed. in English) · 2021Article
- Organic Electrochemistry: Molecular Syntheses with Potential.ACS central science · 2021Review
- Electrooxidative Rhodium-Catalyzed [5+2] Annulations via C-H/O-H Activations.Angewandte Chemie (International ed. in English) · 2021Article
- Facilitating Ir-Catalyzed C-H Alkynylation with Electrochemistry: Anodic Oxidation-Induced Reductive Elimination.ACS catalysis · 2020Article
- Nickela-electrocatalyzed Mild C-H Alkylations at Room Temperature.Angewandte Chemie (International ed. in English) · 2020Article
- Renewable resources for sustainable metallaelectro-catalysed C-H activation.Chemical science · 2020Review
- Insights into Cobalta(III/IV/II)-Electrocatalysis: Oxidation-Induced Reductive Elimination for Twofold C-H Activation.Angewandte Chemie (International ed. in English) · 2020Article
- Mechanistic details of the cobalt-mediated dehydrogenative dimerization of aminoquinoline-directed benzamides.Chemical science · 2020Article
- Carboxylate breaks the arene C-H bondChemical science · 2020Article
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Authors and funding
4 authors.
Funding
Abstract
The merger of cobalt-catalyzed C-H activation and electrosynthesis provides new avenues for resource-economical molecular syntheses, unfortunately their reaction mechanisms remain poorly understood. Herein, we report the identification and full characterization of electrochemically generated high-valent cobalt(III/IV) complexes as crucial intermediates in electrochemical cobalt-catalyzed C-H oxygenations. Detailed mechanistic studies provided support for an oxidatively-induced reductive elimination via highly-reactive cobalt(IV) intermediates. These key insights set the stage for unprecedented cobaltaelectro two-fold C-H/C-H activation.
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