ArticleJournal of the American Chemical Society2020
Evolution of a Strategy for the Enantioselective Synthesis of (-)-Cajanusine.
Article in Journal of the American Chemical Society, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Methylations with methanol via bioinspired catalytic C-O bond cleavage.Nature communications · 2025Article
- Recent advances in the application of [2 + 2] cycloaddition in the chemical synthesis of cyclobutane-containing natural products.Natural products and bioprospecting · 2024Review
- Mechanisms for radical reactions initiating fromBeilstein journal of organic chemistry · 2024Article
- Tandem Isomerization/α,β-Site-Selective and Enantioselective Addition Reactions ofJournal of the American Chemical Society · 2023Article
- Lewis Acid-Promoted [2 + 2] Cycloadditions of Allenes and Ketenes: Versatile Methods for Natural Product Synthesis.Accounts of chemical research · 2023Article
- Stereoselective [2+2]-Cycloadditions of chiral allenic ketones and alkenes: Applications towards the synthesis of benzocyclobutenes and endiandric acids.Tetrahedron · 2022Article
- Enantioselective Synthesis of (+)-Hippolide J and Reevaluation of Antifungal Activity.Organic letters · 2020Article
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Authors and funding
3 authors.
Funding
Abstract
The first enantioselective synthesis of (-)-cajanusine is presented. Key features of the route include a rapid synthesis of the [4.2.0]bicyclooctane core by an enantioselective isomerization/stereoselective [2+2]-cycloaddition strategy as well as prominent use of catalytic methods for bond construction. The evolution of the approach is also presented that highlights unexpected roadblocks and how novel solutions were developed.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.