Evidence map›Paper›PMID 32140827›Full record

ArticleMikrochimica acta2020

Bio-metal-organic frameworks for molecular recognition and sorbent extraction of hydrophilic vitamins followed by their determination using HPLC-UV.

Héctor Martínez Pérez-Cejuela, Marta Mon, Jesús Ferrando-Soria, Emilio Pardo, Donatella Armentano, Ernesto F Simó-Alfonso, José Manuel Herrero-Martínez

Open access · greenAbstract read
PubMed Publisher
In one paragraph

Article in Mikrochimica acta, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
1.2field-weighted citation impact, top 24% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed, 28 citations in OpenAlex.

  1. Review
  2. Review
  3. Article
  4. Article
  5. Article
  6. Review
  7. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors at 3 institutions in 2 countries.

Héctor Martínez Pérez-CejuelaDepartment of Analytical Chemistry, University of Valencia, c/Dr. Moliner, 50, 46100, Valencia, Burjassot, Spain.ORCID https://orcid.org/0000-0002-6456-0846
Marta MonDepartment of Inorganic Chemistry, Institute of Molecular Science (ICMOL), University of Valencia, c/Catedrático José Beltrán 2, 46980, Valencia, Paterna, Spain.ORCID https://orcid.org/0000-0002-1983-1096
Jesús Ferrando-SoriaDepartment of Inorganic Chemistry, Institute of Molecular Science (ICMOL), University of Valencia, c/Catedrático José Beltrán 2, 46980, Valencia, Paterna, Spain.ORCID https://orcid.org/0000-0003-0987-2764
Emilio PardoDepartment of Inorganic Chemistry, Institute of Molecular Science (ICMOL), University of Valencia, c/Catedrático José Beltrán 2, 46980, Valencia, Paterna, Spain. emilio.pardo@uv.es.ORCID https://orcid.org/0000-0002-1394-2553
Donatella ArmentanoDipartimento di Chimica e Tecnologie Chimiche (CTC), Università della Calabria, 87036, Rende, Cosenza, Italy.ORCID https://orcid.org/0000-0002-8502-8074
Ernesto F Simó-AlfonsoDepartment of Analytical Chemistry, University of Valencia, c/Dr. Moliner, 50, 46100, Valencia, Burjassot, Spain.ORCID https://orcid.org/0000-0001-7502-6350
José Manuel Herrero-MartínezDepartment of Analytical Chemistry, University of Valencia, c/Dr. Moliner, 50, 46100, Valencia, Burjassot, Spain. jmherrer@uv.es.ORCID https://orcid.org/0000-0002-8745-3795
Parc Científic de la Universitat de València · ESUniversitat de València · ESUniversity of Calabria · IT

Funding

Conselleria d'Educació, Investigació, Cultura i Esport PROMETEO/2016/145European Research CouncilMinisterio de Ciencia, Innovación y Universidades RTI2018-095536-B-I00
6 · The paper itself

Abstract

A bio-metal-organic framework (bio-MOF) derived from the amino acid L-serine has been prepared in bulk form and evaluated as sorbent for the molecular recognition and extraction of B-vitamins. The functional pores of bio-MOF exhibit high amounts of hydroxyl groups jointly directing other supramolecular host-guest interactions thus providing the recognition of B-vitamins in fruit juices and energy drinks. Single-crystal X-ray diffraction studies reveal the specific B-vitamin binding sites and the existence of multiple hydrogen bonds between these target molecules and the framework. It offered unique snapshots to accomplish an efficient capture of these solutes in complex aqueous matrices. Four B-vitamins (thiamin, nicotinic acid, nicotinamide, and pyridoxine) were investigated. They were eluted from the sorbent with phosphate buffer at pH 7 and analyzed by HPLC with UV detection. The sorbent was compared with commercial C18 cartridges. Following the procedure, acceptable reproducibility (RSD values < 14%) was achieved, and the detection limits were in the range 0.4 to 1.4 ng mL

Indexed as

AdsorptionHydrophobic and Hydrophilic InteractionsMetal-Organic FrameworksParticle SizeSurface PropertiesUltraviolet RaysVitamin B ComplexMetal-Organic FrameworksVitamin B ComplexBio-MOFFunctional beveragesHILICHost-guest interactionL-serineSample preparationSingle-crystal X-ray diffractionSolid-phase extractionWater-soluble vitamins

Identifiers

PMID32140827
OpenAlexW3009197701

What OpenQuestion holds

Textmetadata
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.