ArticleJournal of the American Chemical Society2020
Photocatalyzed Diastereoselective Isomerization of Cinnamyl Chlorides to Cyclopropanes.
Article in Journal of the American Chemical Society, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
15 citing papers in PubMed.
- Triplet Energy Transfer Strategy for Visible Light Activation of Bio-Based Oxime Esters in Photopolymerization and 3D Printing.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Photogenerated Oxetanes as a Gateway to Uphill Cyclopropanation.Angewandte Chemie (International ed. in English) · 2026Article
- Article
- Fundamental Study of Density Functional Theory Applied to Triplet State Reactivity: Introduction of the TRIP50 Data Set.Journal of chemical theory and computation · 2026Article
- Deuterated Cyclopropanation of Alkenes by Iron Catalysis.Organic letters · 2026Article
- The Curious Case of β-Boryl Triplet States.Trends in chemistry · 2025Article
- Synthesis of Borylated Orphaned Cyclopropanes through a Boron-Enabled Cycloisomerization Reaction.Journal of the American Chemical Society · 2025Article
- Mechanistic investigations of polyaza[7]helicene in photoredox and energy transfer catalysis.Beilstein journal of organic chemistry · 2024Article
- Photosensitized OScience (New York, N.Y.) · 2023Article
- Photocatalytic Sulfonyl Fluorination of Alkyl Organoboron Substrates.ACS catalysis · 2023Article
- Accumulation of mono-reduced [Ir(piq)Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology · 2022Article
- Vinylcyclopropane [3+2] Cycloaddition with Acetylenic Sulfones Based on Visible Light Photocatalysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Photostable Ruthenium(II) Isocyanoborato Luminophores and Their Use in Energy Transfer and Photoredox Catalysis.JACS Au · 2021Article
- A Widely Applicable Dual Catalytic System for Cross-Electrophile Coupling Enabled by Mechanistic Studies.ACS catalysis · 2020Article
- Photoinduced Palladium-Catalyzed Carbofunctionalization of Conjugated Dienes Proceeding via Radical-Polar Crossover Scenario: 1,2-Aminoalkylation and Beyond.Journal of the American Chemical Society · 2020Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
6 authors.
Funding
Abstract
Endergonic isomerizations are thermodynamically unfavored processes that are difficult to realize under thermal conditions. We report a photocatalytic and diastereoselective isomerization of acyclic cinnamyl chlorides to strained cyclopropanes. Quantum mechanical calculations (uM06-2X and DLPNO), including TD-DFT calculations, and experimental studies provide evidence for the energy transfer from an iridium photocatalyst to the allylic chloride substrate followed by C-Cl homolytic cleavage. Subsequent Cl
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.