Evidence map›Paper›PMID 32129920›Full record

ArticleAngewandte Chemie (International ed. in English)2020

Singlet Fission in Carbene-Derived Diradicaloids.

Tobias Ullrich, Piermaria Pinter, Julian Messelberger, Philipp Haines, Ramandeep Kaur, Max M Hansmann, Dominik Munz, Dirk M Guldi

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 23 papers.

0numbers the graph read from it
0cells of the map it votes in
23citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

23 citing papers in PubMed.

  1. Article
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  7. Properties and applications of [Beilstein journal of organic chemistry · 2026
    Review
  8. Article
  9. Article
  10. Article
  11. Article
  12. Gauging Radical Stabilization with Carbenes.Angewandte Chemie (International ed. in English) · 2022
    Article
  13. Isolation of an Arsenic Diradicaloid with a Cyclic CAngewandte Chemie (International ed. in English) · 2022
    Article
  14. Article
  15. Article
  16. Article
  17. Review
  18. Review
  19. Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Tobias UllrichDepartment of Chemistry and Pharmacy Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058, Erlangen, Germany.
Piermaria PinterDepartment of Chemistry and Pharmacy Interdisciplinary Center for Molecular Materials (ICMM), Allgemeine und Anorganische Chemie, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 1, 91058, Erlangen, Germany.
Julian MesselbergerDepartment of Chemistry and Pharmacy Interdisciplinary Center for Molecular Materials (ICMM), Allgemeine und Anorganische Chemie, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 1, 91058, Erlangen, Germany.
Philipp HainesDepartment of Chemistry and Pharmacy Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058, Erlangen, Germany.
Ramandeep KaurDepartment of Chemistry and Pharmacy Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058, Erlangen, Germany.
Max M HansmannFakultät für Chemie und Chemische Biologie, Technische Universität Dortmund, Otto-Hahn Straße 6, 44227, Dortmund, Germany.ORCID http://orcid.org/0000-0003-3107-1445
Dominik MunzDepartment of Chemistry and Pharmacy Interdisciplinary Center for Molecular Materials (ICMM), Allgemeine und Anorganische Chemie, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 1, 91058, Erlangen, Germany.ORCID http://orcid.org/0000-0003-3412-651X
Dirk M GuldiDepartment of Chemistry and Pharmacy Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058, Erlangen, Germany.ORCID http://orcid.org/0000-0002-3960-1765

Funding

Deutsche Forschungsgemeinschaft SFB 583
6 · The paper itself

Abstract

Herein, we present a new class of singlet fission (SF) materials based on diradicaloids of carbene scaffolds, namely cyclic (alkyl)(amino)carbenes (CAACs). Our modular approach allows the tuning of two key SF criteria: the steric factor and the diradical character. In turn, we modified the energy landscapes of excited states in a systematic manner to accommodate the needs for SF. We report the first example of intermolecular SF in solution by dimer self-assembly at cryogenic temperatures.

Indexed as

carbenesdiradicaloidsenergy conversionself-assemblysinglet fission

Identifiers

PMID32129920
PMCPMC7317569

What OpenQuestion holds

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Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.