ArticleAngewandte Chemie (International ed. in English)2020
Azaruthena(II)-bicyclo[3.2.0]heptadiene: Key Intermediate for Ruthenaelectro(II/III/I)-catalyzed Alkyne Annulations.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed.
- Substrate-Controlled Rh(III)-Catalyzed Regioselective Synthesis of Benzimidazole-5-carboxylic Acid with Iodonium Ylide toward Benzimidazole-Fused Isochromenes and Isoquinolines.The Journal of organic chemistry · 2026Article
- Electrochemical Enantioselective Ruthenium(II)-Catalyzed C-H Activations to Atropostable Indoles and Chiral Spiropyrazolones.Journal of the American Chemical Society · 2026Article
- Transition-Metal-Catalyzed C-H/N-H Annulation Reactions between Imidazoles and Alkynes for the Synthesis of Fluorescent Benzimidazo[2,1‑ACS omega · 2026Review
- Electrochemical Annulation of Phenothiazines with Alkynes: Access to Anti-Kasha Triple-Emission, Light-Sensitive, and Room-Temperature Phosphorescent Materials.Journal of the American Chemical Society · 2025Article
- Unlocking Catalysis Using Oxidatively Induced Reductive Elimination.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Review
- Green advancements towards the electrochemical synthesis of heterocycles.RSC advances · 2024Review
- Electrochemical Late-Stage Functionalization.Chemical reviews · 2023Review
- Heterocyclic Electrochemistry: Renewable Electricity in the Construction of Heterocycles.ACS omega · 2023Review
- Silver-Free C-H Activation: Strategic Approaches towards Realizing the Full Potential of C-H Activation in Sustainable Organic Synthesis.Angewandte Chemie (International ed. in English) · 2022Review
- Recent Advances in the Synthesis of Isoquinoline-Fused Benzimidazoles.Molecules (Basel, Switzerland) · 2022Review
- 1,2-Difunctionalizations of alkynes entailing concomitant C-C and C-N bond-forming carboamination reactions.RSC advances · 2022Review
- Advances on the Merger of Electrochemistry and Transition Metal Catalysis for Organic Synthesis.Chemical reviews · 2022Review
- A Strategy for Site- and Chemoselective C-H Alkenylation through Osmaelectrooxidative Catalysis.Angewandte Chemie (International ed. in English) · 2021Article
- Mediator-Enabled Electrocatalysis with Ligandless Copper for Anaerobic Chan-Lam Coupling Reactions.Journal of the American Chemical Society · 2021Article
- Organic Electrochemistry: Molecular Syntheses with Potential.ACS central science · 2021Review
- Electrooxidative Rhodium-Catalyzed [5+2] Annulations via C-H/O-H Activations.Angewandte Chemie (International ed. in English) · 2021Article
- Ruthenaelectro-Catalyzed Domino Three-Component Alkyne Annulation for Expedient Isoquinoline Assembly.Angewandte Chemie (International ed. in English) · 2021Article
- Divergent rhodium-catalyzed electrochemical vinylic C-H annulation of acrylamides with alkynes.Nature communications · 2021Article
- Renewable resources for sustainable metallaelectro-catalysed C-H activation.Chemical science · 2020Review
- Azaruthena(II)-bicyclo[3.2.0]heptadiene: Key Intermediate for Ruthenaelectro(II/III/I)-catalyzed Alkyne Annulations.Angewandte Chemie (International ed. in English) · 2020Article
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7 authors.
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Abstract
A ruthenium-catalyzed electrochemical dehydrogenative annulation reaction of imidazoles with alkynes has been established, enabling the preparation of various bridgehead N-fused [5,6]-bicyclic heteroarenes through regioselective electrochemical C-H/N-H annulation without chemical metal oxidants. Novel azaruthenabicyclo[3.2.0]heptadienes were fully characterized and identified as key intermediates. Mechanistic studies are suggestive of an oxidatively induced reductive elimination pathway within a ruthenium(II/III) regime.
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