ArticleAngewandte Chemie (International ed. in English)2020
C-H Bond Activation by an Imido Cobalt(III) and the Resulting Amido Cobalt(II) Complex.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed, 65 citations in OpenAlex.
- Nitrene-Transfer Chemistry to Olefins Mediated by Co(III) Catalysts Supported by a Tetraamido Macrocycle.Inorganic chemistry · 2026Article
- Transient Triamidoamine Neptunium(V)-Mono(Imido) Complexes: C-H Activations and Hydrogen Atom Transfer Driven by Effective Nuclear Charge.Journal of the American Chemical Society · 2026Article
- Four-Coordinate Co(III) Imide with an Unusually Tilted Terminal Imido Ligand.Organometallics · 2024Article
- Generation, Spectroscopic Characterization, and Computational Analysis of a Six-Coordinate Cobalt(III)-Imidyl Complex with an UnusualJournal of the American Chemical Society · 2023Article
- Umpolung in a Pair of Cobalt(III) Terminal Imido/Imidyl Complexes.Angewandte Chemie (International ed. in English) · 2022Article
- CInorganic chemistry · 2022Article
- Between imide, imidyl and nitrene - an imido iron complex in two oxidation states.Chemical science · 2022Article
- Cationic Effects on the Net Hydrogen Atom Bond Dissociation Free Energy of High-Valent Manganese Imido Complexes.Journal of the American Chemical Society · 2022Article
- Cobalt and Iron Stabilized Ketyl, Ketiminyl and Aldiminyl Radical Anions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- A Pair of Cobalt(III/IV) Terminal Imido Complexes.Angewandte Chemie (International ed. in English) · 2021Article
- High-Spin Imido Cobalt Complexes with Imidyl Radical Character*.Angewandte Chemie (International ed. in English) · 2021Article
- Is the Electrophilicity of the Metal Nitrene the Sole Predictor of Metal-Mediated Nitrene Transfer to Olefins? Secondary Contributing Factors as Revealed by a Library of High-Spin Co(II) Reagents.Organometallics · 2021Article
- Reductive Coupling of (Fluoro)pyridines by Linear 3d-Metal(I) Silylamides of Cr-Co: A Tale of C-C Bond Formation, C-F Bond Cleavage and a Pyridyl Radical Anion.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Fluoro Nitrenoid Complexes FN=MFAngewandte Chemie (International ed. in English) · 2020Article
- C-H Bond Activation by an Imido Cobalt(III) and the Resulting Amido Cobalt(II) Complex.Angewandte Chemie (International ed. in English) · 2020Article
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
Abstract
The 3d-metal mediated nitrene transfer is under intense scrutiny due to its potential as an atom economic and ecologically benign way for the directed amination of (un)functionalised C-H bonds. Here we present the isolation and characterisation of a rare, trigonal imido cobalt(III) complex, which bears a rather long cobalt-imido bond. It can cleanly cleave strong C-H bonds with a bond dissociation energy of up to 92 kcal mol
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.