ArticleChemical science2019
Well-distributed Pt-nanoparticles within confined coordination interspaces of self-sensitized porphyrin metal-organic frameworks: synergistic effect boosting highly efficient photocatalytic hydrogen evolution reaction.
Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Facile and Fast Microwave-Assisted Synthesis of Metalated PCN-222 for Light-Driven Hydrogen Evolution Reaction.ACS omega · 2026Article
- Tuning the Photoelectrochemical Properties of Ti/W-Modified PCN-222 Using Charge-Selective Interfaces.ACS applied materials & interfaces · 2026Article
- Fabricating Inorganic/Organic S-Scheme Heterojunction for Efficient Photocatalytic Production of HResearch (Washington, D.C.) · 2026Article
- The ZrChemSusChem · 2025Article
- Nanoconfinement Effects in Electrocatalysis and Photocatalysis.Small (Weinheim an der Bergstrasse, Germany) · 2025Review
- Porphyrin-Based Metal-Organic Framework Materials: Design, Construction, and Application in the Field of Photocatalysis.Molecules (Basel, Switzerland) · 2024Review
- Enhancing the Photocatalytic Activity of Zirconium-Based Metal-Organic Frameworks Through the Formation of Mixed-Valence Centers.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
- Metal-Organic Frameworks as Photocatalysts for Solar-Driven Overall Water Splitting.Chemical reviews · 2023Review
- Turn-On Photocatalysis: Creating Lone-Pair Donor-Acceptor Bonds in Organic Photosensitizer to Enhance Intersystem Crossing.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2021Article
- A historical perspective on porphyrin-based metal-organic frameworks and their applications.Coordination chemistry reviews · 2021Article
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Authors and funding
7 authors.
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Abstract
Effective conversion of solar energy into chemical energy by visible light represents a potential strategy for sustainable development. Among which, photocatalytic hydrogen evolution reaction (HER) with a relatively small activation energy (1.23 eV, around 1000 nm light irradiation) is especially attractive. In this work, well-distributed platinum nanoparticles (Pt-NPs) with a width of about 3 nm have been successfully immobilized into the confined coordination interspaces of 3.7 nm diameter, which are facilitated by early transition metal Hf(iv)-based clusters of a self-sensitized palladium porphyrin metal-organic framework. Under visible light irradiation, the resultant Pt@Pd-PCN-222(Hf) (which is also denoted as Pt@Pd-PMOF-2(Hf)) displays superb photocatalytic activity, achieving an unprecedented maximum H
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