ArticleChemical science2019
Aerobic C-C and C-O bond formation reactions mediated by high-valent nickel species.
Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed, 42 citations in OpenAlex.
- Aerobic C-H bond activation at a Pd center under aqueous conditions.Chemical science · 2026Article
- Article
- Comparative Nitrene-Transfer Chemistry to Olefins Mediated by First-Row Transition Metal Catalysts Supported by a Pyridinophane Macrocycle with N4 Ligation.Molecules (Basel, Switzerland) · 2025Article
- Rapid Oxygen Atom Transfer at a Catalysis-Relevant Ni(I)-Alkyl Complex with NJournal of the American Chemical Society · 2025Article
- Appended Lewis Acids Enable Dioxygen Reactivity and Catalytic Oxidations with Ni(II).Journal of the American Chemical Society · 2024Article
- Oxygen transfer reactivity mediated by nickel perfluoroalkyl complexes using molecular oxygen as a terminal oxidant.Chemical science · 2023Article
- Deciphering the mechanism of the Ni-photocatalyzed C‒O cross-coupling reaction using a tridentate pyridinophane ligand.Nature communications · 2022Article
- Dialkyl Ether Formation at High-Valent Nickel.Journal of the American Chemical Society · 2020Article
- High-Valent NiMolecules (Basel, Switzerland) · 2020Review
- Effect of 4-Position Pyridine Ring Substitution on Zn(II) Complexes of 4-substituted PyJournal of coordination chemistryArticle
Corrections and comments
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Authors and funding
6 authors at 4 institutions in 3 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Nickel complexes have been widely employed as catalysts in C-C and C-heteroatom bond formation reactions. While Ni(0), Ni(i), and Ni(ii) intermediates are most relevant in these transformations, recently Ni(iii) and Ni(iv) species have also been proposed to play a role in catalysis. Reported herein is the synthesis, detailed characterization, and reactivity of a series of Ni(ii) and Ni(iii) metallacycle complexes stabilized by tetradentate pyridinophane ligands with various N-substituents. Interestingly, while the oxidation of the Ni(ii) complexes with various other oxidants led to exclusive C-C bond formation in very good yields, the use of O
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Registered trials
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