Evidence map›Paper›PMID 32092731›Full record

ArticleAnalytical sciences : the international journal of the Japan Society for Analytical Chemistry2020

Measuring the Henry's Law Constant for Carbon Dioxide and Water with UV-visible Absorption Spectroscopy.

Albert D Dukes

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Article in Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

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2citing papers in PubMed
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1 · What the graph read from it

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3 · Its place in the literature

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2 citing papers in PubMed.

  1. Tunable and Efficient COBiotechnology and bioengineering · 2026
    Article
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4 · The record

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5 · Who and what money

Authors and funding

1 author.

Albert D DukesDepartment of Physical Sciences, Lander University, 320 Stanley Ave., Greenwood, SC, 29649, USA.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The Henry's law constant defines the solubility of a gas in a liquid solution. In this study, a new method for measuring the Henry's law constant is described. This new colorimetric method is suited for gases which react with water to form acidic or basic solutions when they dissolve, and makes use of measuring the concentration of two forms of a colorimetric pH indicator. By measuring the concentration of the protonated and deprotonated forms of the indicator with UV-visible absorption spectroscopy, the concentration of the hydronium in solution was determined. After determining the hydronium concentration, the equilibrium expression for the dissolved gas reacting with water was solved to determine the concentration of the dissolved gas. The concentration of the dissolved gas and the measured partial pressure of the dissolved gas at equilibrium were then used to calculate the Henry's law constant for the gas. The efficacy of the method is demonstrated by measuring the Henry's law constant for carbon dioxide in water over a range of pressures (0.680 - 5.10 atm). The results obtained with this method are comparable to the value for the Henry's law constant that have been previously reported via more traditional methods, and yielded values for the Henry's law constant for carbon dioxide that ranged from 3.45 × 10

Indexed as

absorption spectroscopyacid-base equilibriumanalytical method developmentcarbon dioxide solubilityHenry’s law constant

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.