Evidence map›Paper›PMID 32083849›Full record

ArticleAnalytical chemistry2020

Effective Temperature and Structural Rearrangement in Trapped Ion Mobility Spectrometry.

Denis Morsa, Emeline Hanozin, Gauthier Eppe, Loïc Quinton, Valérie Gabelica, Edwin De Pauw

Abstract read
PubMed Publisher
In one paragraph

Article in Analytical chemistry, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.

0numbers the graph read from it
0cells of the map it votes in
22citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

22 citing papers in PubMed.

  1. Article
  2. Article
  3. Collision-Induced Unfolding of High-Journal of the American Society for Mass Spectrometry · 2025
    Article
  4. Mobility-Assisted Pseudo-MSJournal of the American Society for Mass Spectrometry · 2024
    Article
  5. Evaluation of a Commercial TIMS-Q-TOF Platform for Native Mass Spectrometry.Journal of the American Society for Mass Spectrometry · 2024
    Article
  6. Article
  7. Article
  8. Article
  9. Article
  10. Article
  11. Article
  12. Article
  13. Article
  14. Review
  15. Article
  16. Review
  17. Article
  18. Article
  19. Article
  20. Review
4 · The record

Corrections and comments

5 · Who and what money

Authors and funding

6 authors.

Denis MorsaMass Spectrometry Laboratory, MolSys Research Unit, University of Liège, Liège 4000, Belgium.ORCID 0000-0002-1944-2760
Emeline HanozinMass Spectrometry Laboratory, MolSys Research Unit, University of Liège, Liège 4000, Belgium.ORCID 0000-0002-7717-9999
Gauthier EppeMass Spectrometry Laboratory, MolSys Research Unit, University of Liège, Liège 4000, Belgium.ORCID 0000-0002-4821-3115
Loïc QuintonMass Spectrometry Laboratory, MolSys Research Unit, University of Liège, Liège 4000, Belgium.ORCID 0000-0001-8153-9590
Valérie GabelicaUniversity of Bordeaux, INSERM and CNRS, Laboratoire Acides Nucléiques: Régulations Naturelles et Artificielles (ARNA, U1212, UMR5320), IECB, Pessac 33600, France.ORCID 0000-0001-9496-0165
Edwin De PauwMass Spectrometry Laboratory, MolSys Research Unit, University of Liège, Liège 4000, Belgium.ORCID 0000-0003-3475-1315

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Modern ion mobility instrumentation is typically operated above the low field limit, which may activate the ions and cause structural rearrangement or fragmentation during analysis. Here, we quantitatively assessed the internal heating experienced by ions during trapped ion mobility spectrometry (TIMS) experiments. To this end, the fragmentation yields of fragile benzylpyridinium "thermometer" ions were monitored during both the accumulation and analysis steps inside the TIMS tunnel. The corresponding fragmentation rate constants were translated into a vibrational effective temperature

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.