ArticleAngewandte Chemie (International ed. in English)2020
Regioselective Arene C-H Alkylation Enabled by Organic Photoredox Catalysis.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 14 papers.
What it found
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Who cites it
14 citing papers in PubMed.
- Electrochemical Single-Carbon Insertion via Distonic Radical Cation Intermediates.Journal of the American Chemical Society · 2025Article
- Arene and Heteroarene Functionalization Enabled by Organic Photoredox Catalysis.Accounts of chemical research · 2025Article
- Synthesis of Biaryl Atropisomers via Site-Selective C-H Functionalization.Organic letters · 2025Article
- One-Step Synthesis of [ACS central science · 2024Article
- Visible Light-Induced Reactions of Diazo Compounds and Their Precursors.Chemical reviews · 2024Review
- Late-stage benzenoid-to-troponoid skeletal modification of the cephalotanes exemplified by the total synthesis of harringtonolide.Nature communications · 2024Article
- Chemodivergent C(spNature catalysis · 2023Article
- Chemoselective Decarboxylative Protonation Enabled by Cooperative Earth-Abundant Element Catalysis.Angewandte Chemie (International ed. in English) · 2023Article
- Photochemical C(spAngewandte Chemie (International ed. in English) · 2022Article
- Highly selective α-aryloxyalkyl C-H functionalisation of aryl alkyl ethers.Chemical science · 2022Article
- Dearomative (3+2) Cycloadditions between Indoles and Vinyldiazo Species Enabled by a Red-Shifted Chromium Photocatalyst.Angewandte Chemie (International ed. in English) · 2022Article
- Photoredox-Catalyzed C-H Functionalization Reactions.Chemical reviews · 2022Review
- Visible-Light Photoredox Catalyzed Dehydrogenative Synthesis of Allylic Carboxylates from Styrenes.Organic letters · 2021Article
- Metal-free tandem carbene N-H insertions and C-C bond cleavages.Chemical science · 2020Article
Corrections and comments
- Erratum issued
Authors and funding
3 authors.
Funding
Abstract
Expanding the toolbox of C-H functionalization reactions applicable to the late-stage modification of complex molecules is of interest in medicinal chemistry, wherein the preparation of structural variants of known pharmacophores is a key strategy for drug development. One manifold for the functionalization of aromatic molecules utilizes diazo compounds and a transition-metal catalyst to generate a metallocarbene species, which is capable of direct insertion into an aromatic C-H bond. However, these high-energy intermediates can often require directing groups or a large excess of substrate to achieve efficient and selective reactivity. Herein, we report that arene cation radicals generated by organic photoredox catalysis engage in formal C-H functionalization reactions with diazoacetate derivatives, furnishing sp
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