Evidence map›Paper›PMID 32065193›Full record

ArticleChemical communications (Cambridge, England)2020

Synthesis and electronic structure studies of a Cr-imido redox series.

Yuyang Dong, Ryan M Clarke, Shao-Liang Zheng, Theodore A Betley

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Article in Chemical communications (Cambridge, England), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Yuyang DongDepartment of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA. betley@chemistry.harvard.edu.ORCID http://orcid.org/0000-0002-4533-4798
Ryan M ClarkeDepartment of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA. betley@chemistry.harvard.edu.ORCID http://orcid.org/0000-0003-3356-071X
Shao-Liang ZhengDepartment of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA. betley@chemistry.harvard.edu.ORCID http://orcid.org/0000-0002-6432-9943
Theodore A BetleyDepartment of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA. betley@chemistry.harvard.edu.ORCID http://orcid.org/0000-0001-5946-9629

Funding

Correlation of electronic structure to iron catalyzed C-H bond functionalizationR01GM115815 · NIGMS · HARVARD UNIVERSITY · PI BETLEY, THEODORE A · 2015 to 2018
$1.3M
NIGMS NIH HHS R01 GM115815
6 · The paper itself

Abstract

The effect of metal identity, d-electron count, and coordination geometry on the electronic structure of a metal-ligand multiple bond (MLMB) is an area of active exploration. Although high oxidation state Cr imidos have been extensively studied, very few reports on low-valent Cr imidos or the interconversion of redox isomers exist. Herein, we report the synthesis and characterization of a family of dipyrrinato Cr imido complexes in oxidation states ranging from CrIII to CrV, showcasing the influence of the weak-field dipyrromethene scaffold on the electronic structure and coordination geometries of these Cr imides.

Identifiers

PMID32065193
PMCPMC7132162

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.