Evidence map›Paper›PMID 32055371›Full record

ArticleChemical science2019

Unusual near infrared (NIR) fluorescent palladium(ii) macrocyclic complexes containing M-C bonds with bioimaging capability.

Yuhang Yao, Chun-Liang Hou, Zi-Shu Yang, Guangliu Ran, Lei Kang, Cuicui Li, Wenkai Zhang, Jing Zhang, Jun-Long Zhang

Open access · diamondAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
1.4field-weighted citation impact, top 20% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed, 27 citations in OpenAlex.

  1. Luminescence and Palladium: The Odd Couple.Molecules (Basel, Switzerland) · 2023
    Review
  2. Review
  3. Neo-Porphyrinoids: New Members of the Porphyrinoid Family.Topics in current chemistry (Cham) · 2021
    Review
  4. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors at 3 institutions in 2 countries.

Yuhang YaoBeijing National Laboratory for Molecular Sciences , State Key Laboratory of Rare Earth Materials Chemistry and Applications , College of Chemistry and Molecular Engineering , Peking University , Beijing 100871 , P. R. China . Email: zhangjunlong@pku.edu.cn.
Chun-Liang HouCenter of Materials Science and Optoelectronics Engineering , College of Materials Science and Opto-Electronic Technology , University of Chinese Academy of Sciences , Beijing 100049 , P. R. China . Email: zhangj271@ucas.ac.cn.
Zi-Shu YangBeijing National Laboratory for Molecular Sciences , State Key Laboratory of Rare Earth Materials Chemistry and Applications , College of Chemistry and Molecular Engineering , Peking University , Beijing 100871 , P. R. China . Email: zhangjunlong@pku.edu.cn.
Guangliu RanCenter for Advanced Quantum Studies , Department of Physics and Applied Optics Beijing Area Major Laboratory , Beijing Normal University , Beijing 100875 , P. R. China . Email: wkzhang@bnu.edu.cn.
Lei KangDepartment of Nuclear Medicine , Peking University First Hospital , Beijing 100034 , P. R. China.
Cuicui LiDepartment of Nuclear Medicine , Peking University First Hospital , Beijing 100034 , P. R. China.
Wenkai ZhangCenter for Advanced Quantum Studies , Department of Physics and Applied Optics Beijing Area Major Laboratory , Beijing Normal University , Beijing 100875 , P. R. China . Email: wkzhang@bnu.edu.cn.ORCID 0000-0002-9574-6272
Jing ZhangCenter of Materials Science and Optoelectronics Engineering , College of Materials Science and Opto-Electronic Technology , University of Chinese Academy of Sciences , Beijing 100049 , P. R. China . Email: zhangj271@ucas.ac.cn.
Jun-Long ZhangBeijing National Laboratory for Molecular Sciences , State Key Laboratory of Rare Earth Materials Chemistry and Applications , College of Chemistry and Molecular Engineering , Peking University , Beijing 100871 , P. R. China . Email: zhangjunlong@pku.edu.cn.ORCID 0000-0002-5731-7354
Peking University · CNBeijing Normal University · CNUniversity of Chinese Academy of Sciences · CN

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Near infrared (NIR) luminescent metal complexes are promising probes in bioimaging and biosensing, however they generally suffer from oxygen interference arising from heavy metal effects. We designed new tetradentate macrocyclic benzitripyrrin (C^N^N^N) ligands by combination of M-C bond formation and reducing the π-conjugation to achieve NIR fluorescent Pd complexes (700-1000 nm) with quantum yields up to 14%. To understand the origin of NIR fluorescence, detailed analyses by density functional theory/time-dependent density functional theory (DFT/TDDFT) calculations together with femtosecond and nanosecond transient absorption spectroscopies suggest that M-C bond formation indeed leads to destabilization of the d-d excited state and less effective quenching of emission; and importantly, small spin-orbital coupling (SOC) and the large singlet-triplet energy gap are the primary causes of the non-population of triplet states. Comparison of Pd

Identifiers

PMID32055371
PMCPMC6979397
OpenAlexW2972759905

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.